Nanoporous copolymer networks through multiple Friedel-Crafts-alkylation-studies on hydrogen and methane storage

作者: Matthias Georg Schwab , Angela Lennert , Jörg Pahnke , Gerhard Jonschker , Matthias Koch

DOI: 10.1039/C0JM03017A

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摘要: A novel series of hypercrosslinked copolymer networks was obtained by the statistical co-condensation 4,4′-bis(chloromethyl)biphenyl with a non-functionalized fluorene-based monomers under Friedel–Crafts catalysis. The resulting nanoporous polymer materials exhibit high BET surface areas up to 1800 m2 g−1 as derived from nitrogen physisorption. hydrogen and methane uptakes were examined respect chemical composition these adsorbents.

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