Phase Quantification of Carbon Support by X-Ray Photoelectron Spectroscopy (XPS) in Plasma-Synthesized Fischer–Tropsch Nanocatalysts

作者: James Aluha , Sonia Blais , Nicolas Abatzoglou

DOI: 10.1007/S10562-018-2428-Y

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摘要: X-ray photoelectron spectroscopy was used to quantify the different types of carbon in Co/C, Fe/C, 30%Co–70%Fe/C and 80%Co–20%Fe/C nanocatalysts synthesized through plasma-spray technology tested for Fischer–Tropsch synthesis. The results showed that metal nanoparticle size influences graphitization C support, on which catalyst’s surface area largely depends.

参考文章(48)
A. V. Syugaev, N. V. Lyalina, S. F. Lomayeva, A. N. Maratkanova, Electrochemical behavior of Co3C carbide Journal of Solid State Electrochemistry. ,vol. 19, pp. 2933- 2941 ,(2015) , 10.1007/S10008-015-2903-Y
V. V. Chesnokov, A. S. Chichkan’, V. I. Zaikovskii, V. N. Parmon, Formation of carbon nanofilaments from C6-C16 alkanes over nickel-containing catalysts Kinetics and Catalysis. ,vol. 54, pp. 213- 219 ,(2013) , 10.1134/S002315841302002X
Jian Chen, Cuihua Xue, Rajagopal Ramasubramaniam, Haiying Liu, A new method for the preparation of stable carbon nanotube organogels Carbon. ,vol. 44, pp. 2142- 2146 ,(2006) , 10.1016/J.CARBON.2006.03.011
Sepideh Jankhah, Nicolas Abatzoglou, François Gitzhofer, Jasmin Blanchard, Hicham Oudghiri-Hassani, Catalytic properties of carbon nano-filaments produced by iron-catalysed reforming of ethanol Chemical Engineering Journal. ,vol. 139, pp. 532- 539 ,(2008) , 10.1016/J.CEJ.2007.08.031
BalSang Lee, Hyun Mo Koo, Myung-June Park, Byungkwon Lim, Dong Ju Moon, Ki June Yoon, Jong Wook Bae, Deactivation Behavior of Co/SiC Fischer–Tropsch Catalysts by Formation of Filamentous Carbon Catalysis Letters. ,vol. 143, pp. 18- 22 ,(2013) , 10.1007/S10562-012-0936-8
Thomas A. Westrich, Xiaoyin Chen, Johannes W. Schwank, Isooctane decomposition and carbon deposition over ceria–zirconia supported nickel catalysts Applied Catalysis A-general. ,vol. 386, pp. 83- 93 ,(2010) , 10.1016/J.APCATA.2010.07.029
D.J. Duvenhage, N.J. Coville, Fe:CoTiO2 bimetallic catalysts for the Fischer-Tropsch reaction I. Characterization and reactor studies Applied Catalysis A: General. ,vol. 153, pp. 43- 67 ,(1997) , 10.1016/S0926-860X(96)00326-2
V. V. Ordomsky, B. Legras, K. Cheng, S. Paul, A. Y. Khodakov, The role of carbon atoms of supported iron carbides in Fischer–Tropsch synthesis Catalysis Science & Technology. ,vol. 5, pp. 1433- 1437 ,(2015) , 10.1039/C4CY01631A
Jianmin Xiong, Yunjie Ding, Tao Wang, Li Yan, Weimiao Chen, Hejun Zhu, Yuan Lu, The formation of Co 2 C species in activated carbon supported cobalt-based catalysts and its impact on Fischer–Tropsch reaction Catalysis Letters. ,vol. 102, pp. 265- 269 ,(2005) , 10.1007/S10562-005-5867-1