In-situ activation of metal complexes containing terdentate nitrogen ligands used as hydrosilylation catalysts

作者: Paul J. Chirik , Keith J. Weller , Aaron M. Tondreau , Kenrick M. Lewis , Johannes G.P. Delis

DOI:

关键词:

摘要: Disclosed herein is a process for the hydrosilylation of composition containing silyl hydride and compound at least one unsaturated group, comprising contacting non-previous metal based complex as catalyst precursor with an activator being reducing agent shortly before, simultaneously or after composition, to cause react group produce product.

参考文章(27)
Larry D. Boardman, Joel D. Oxman, Radiation activated hydrosilation reaction ,(1991)
Harry Van Der Heijden, Marijke De Boer-Wildschut, Eric Johannes Maria De Boer, Arie Van Zon, Catalyst systems for ethylene oligomerisation to linear alpha olefins ,(2003)
Alex Sergey Ionkin, Lynda Kaye Johnson, Catalysts for olefin polymerization or oligomerization ,(2005)
William M. Reiff, N. E. Erickson, Willie Arthur Baker, Mono(2,2',2"-terpyridine) complexes of iron(II) Inorganic Chemistry. ,vol. 8, pp. 2019- 2021 ,(1969) , 10.1021/IC50079A046
E.C. Chukovskaya, R.G. Petrova, A.B. Belyavsky, A.N. Nesmeyanov, R.Kh. Freidlina, Addition, substitution, and telomerization reactions of olefins in the presence of metal carbonyls or colloidal iron Tetrahedron. ,vol. 17, pp. 61- 68 ,(1962) , 10.1016/S0040-4020(01)99004-0
Andrew M. Archer, Marco W. Bouwkamp, Maria-Patricia Cortez, Emil Lobkovsky, Paul J. Chirik, Arene Coordination in Bis(imino)pyridine Iron Complexes: Identification of Catalyst Deactivation Pathways in Iron-Catalyzed Hydrogenation and Hydrosilation Organometallics. ,vol. 25, pp. 4269- 4278 ,(2006) , 10.1021/OM060441C
Roswitha Kröll, Christian Eschbaumer, Ulrich S. Schubert, Michael R. Buchmeiser, Klaus Wurst, Access to Heterogeneous Atom-Transfer Radical Polymerization (ATRP) Catalysts Based on Dipyridylamine and Terpyridine via Ring-Opening Metathesis Polymerization (ROMP) Macromolecular Chemistry and Physics. ,vol. 202, pp. 645- 653 ,(2001) , 10.1002/1521-3935(20010301)202:5<645::AID-MACP645>3.0.CO;2-X