Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation

作者: Paul J. Chirik , Keith J. Weller , Kenrick Lewis , Aroop Kumar Roy , Johannes G.P. Delis

DOI:

关键词:

摘要: Disclosed herein are cobalt complexes containing pyridine di-imine ligands and chelating alkenyl-modified silyl ligands, their use as hydrosilylation and/or dehydrogenative silylation crosslinking catalysts. The also exhibit adequate air stability for handling manipulation.

参考文章(146)
Crisita Carmen Hojilla Atienza, Reactivity of bis(imino)pyridine cobalt complexes in C-H bond activation and catalytic C-C and C-Si bond formation Princeton, NJ : Princeton University. ,(2013)
Enrique Iglesia, István T. Horváth, Encyclopedia of catalysis Wiley. ,(2003)
조은정, 송순정, 정일남, 우희권, Redistribution of Bis- and Tris(silyl)methanes Catalyzed by Red-Al Bulletin of The Korean Chemical Society. ,vol. 17, pp. 123- 125 ,(1996)
Paul Chirik, Crisita Carmen H. Atienza, Keith James Weller, Julie Boyer, Kenrick Lewis, Johannes G.P. Delis, Susan A. Nye, Non-precious Metal-based Hyrdosilylation Catalysts Exhibiting Improved Selectivity ,(2011)
Paul J. Chirik, Keith J. Weller, Renyuan Yu, Kenrick Lewis, Aroop Kumar Roy, Johannes G. P. Delis, Tianning Diao, Susan Nye, Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts ,(2014)
Paul J. Chirik, Max R. Friedfeld, Jordan M. Hoyt, Sebastien Monfette, Enantiopure base-metal catalysts for asymmetric catalysis and bis(imino)pyridine iron alkyl complexes for catalysis ,(2012)
Paul J. Chirik, Keith J. Weller, Aaron M. Tondreau, Kenrick M. Lewis, Johannes G.P. Delis, Susan A. Nye, In-situ activation of metal complexes containing terdentate nitrogen ligands used as hydrosilylation catalysts ,(2011)