Structural defects-mediated room-temperature ferromagnetism in Co-doped SnO2 insulating films

作者: X.F. Liu , W.M. Gong , Javed Iqbal , B. He , R.H. Yu

DOI: 10.1016/J.TSF.2009.05.008

关键词:

摘要: Abstract Co-doped SnO 2 insulating films with different crystal quality were fabricated using magnetron sputtering. X-ray photoelectron spectroscopy and absorption near-edge structure spectrum reveal a solid solution of Co dopants in lattice, where is 2+ oxidation state substitutes for Sn 4+ . The as-grown crystallinity exhibit clearly room-temperature ferromagnetism, the more structural defects show higher saturated magnetic moment. With increase annealing time, improved decrease, leading to decrease or disappearance ferromagnetism films. results that intrinsic can be considerably influenced by concentration defects.

参考文章(22)
S. B. Ogale, R. J. Choudhary, J. P. Buban, S. E. Lofland, S. R. Shinde, S. N. Kale, V. N. Kulkarni, J. Higgins, C. Lanci, J. R. Simpson, N. D. Browning, S. Das Sarma, H. D. Drew, R. L. Greene, T. Venkatesan, High temperature ferromagnetism with a giant magnetic moment in transparent co-doped SnO(2-delta). Physical Review Letters. ,vol. 91, pp. 077205- ,(2003) , 10.1103/PHYSREVLETT.91.077205
H. Y. Xu, Y. C. Liu, C. S. Xu, Y. X. Liu, C. L. Shao, R. Mu, Room-temperature ferromagnetism in (Mn, N)-codoped ZnO thin films prepared by reactive magnetron cosputtering Applied Physics Letters. ,vol. 88, pp. 242502- ,(2006) , 10.1063/1.2213929
François Farges, Gordon E. Brown, J. J. Rehr, TI K-EDGE XANES STUDIES OF TI COORDINATION AND DISORDER IN OXIDE COMPOUNDS: COMPARISON BETWEEN THEORY AND EXPERIMENT Physical Review B. ,vol. 56, pp. 1809- 1819 ,(1997) , 10.1103/PHYSREVB.56.1809
XF Liu, RH Yu, None, Mediation of room temperature ferromagnetism in Co-doped SnO2 nanocrystalline films by structural defects Journal of Applied Physics. ,vol. 102, pp. 083917- ,(2007) , 10.1063/1.2801375
Hyun-Suk Kim, Lei Bi, G. F. Dionne, C. A. Ross, Han-Jong Paik, Structure, magnetic and optical properties, and Hall effect of Co- and Fe-doped SnO 2 films Physical Review B. ,vol. 77, pp. 214436- ,(2008) , 10.1103/PHYSREVB.77.214436
J. W. Quilty, A. Shibata, J.-Y. Son, K. Takubo, T. Mizokawa, H. Toyosaki, T. Fukumura, M. Kawasaki, Signature of carrier-induced ferromagnetism in Ti1-xCoxO2-δ : Exchange interaction between high-spin Co2+ and the Ti 3d conduction band Physical Review Letters. ,vol. 96, pp. 027202- ,(2006) , 10.1103/PHYSREVLETT.96.027202
Yuji Matsumoto, Makoto Murakami, Tomoji Shono, Tetsuya Hasegawa, Tomoteru Fukumura, Masashi Kawasaki, Parhat Ahmet, Toyohiro Chikyow, Shin-ya Koshihara, Hideomi Koinuma, Room-Temperature Ferromagnetism in Transparent Transition Metal-Doped Titanium Dioxide Science. ,vol. 291, pp. 854- 856 ,(2001) , 10.1126/SCIENCE.1056186
KA Griffin, AB Pakhomov, CM Wang, SM Heald, Kannan M Krishnan, None, Intrinsic Ferromagnetism in Insulating Cobalt Doped Anatase TiO~2 Physical Review Letters. ,vol. 94, pp. 157204- ,(2005) , 10.1103/PHYSREVLETT.94.157204
S. T. Lee, R. Sammynaiken, T. K. Sham, Y. F. Zhang, L. S. Liao, W. H. Chan, Electronic structure of silicon nanowires: A photoemission and x-ray absorption study Physical Review B. ,vol. 61, pp. 8298- 8305 ,(2000) , 10.1103/PHYSREVB.61.8298
Jung-Chun Andrew Huang, HS Hsu, JH Sun, SL Chiu, CH Lee, YF Liao, Hsiung Chou, None, Study of the local environment diversity between Co- and Mn-doped ZnO single crystal film by multilayer growth technique Journal of Applied Physics. ,vol. 103, ,(2008) , 10.1063/1.2834708