Working Supramolecular Machines Trapped in Glass and Mounted on a Film Surface
作者： Shinye Chia , Jianguo Cao , J. Fraser Stoddart , Jeffrey I. Zink
DOI: 10.1002/1521-3773(20010702)40:13<2447::AID-ANIE2447>3.0.CO;2-P
关键词:
摘要: Two surface-tethered nanomachines have been constructed at a supramolecular level by employing cylinders of the π-electron deficient tetracationic cyclophane, cyclobis(paraquat-p-phenylene) (blue), inside which polyether pistons incorporating rich dioxynaphthalene units (red and pink) can be induced to move when reductants are supplied either chemicals or from light source with 9-anthracenecarboxylic acid (yellow) as photosensitizer ethylenediaminetetraacetate (green) sacrificial reagent.
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