Synthesis and characterization of tris(2-pyridylthio)methanido Zn complex with a Zn–C bond and DFT calculation of its one-electron oxidized species
作者： Ken’ichi Kitano , Naoto Kuwamura , Rika Tanaka , Ryoko Santo , Takanori Nishioka
DOI: 10.1039/B715996J
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摘要: Tris(2-pyridylthio)methane (tptmH) reacts with ZnCl2 producing the Zn–C containing complex of [ZnCl(tptm)], whose cyclic voltammogram shows an irreversible oxidation peak at 0.2 V vs. E0′(Fc+/0). DFT calculations suggested that 1e−oxidation should occur tptm ligand resulting in cleavage bond, leading to decomposition complex.
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Nobumasa Kitajima, William B. Tolman, Coordination Chemistry with Sterically Hindered Hydrotris(pyrazolyl)borate Ligands: Organometallic and Bioinorganic Perspectives Progress in Inorganic Chemistry. pp. 419- 531 ,(2007) , 10.1002/9780470166444.CH5
Isamu Kinoshita, L. James Wright, Sachiko Kubo, Kentaro Kimura, Akio Sakata, Toshihiro Yano, Riichi Miyamoto, Takanori Nishioka, Kiyoshi Isobe, Design and synthesis of copper complexes of novel ligands based on the pyridine thiolate group Dalton Transactions. pp. 1993- 2003 ,(2003) , 10.1039/B210420M
Juan C Mareque Rivas, Emiliano Salvagni, Rafael Torres Martín de Rosales, Simon Parsons, None, Internal hydrogen bonding in tetrahedral and trigonal bipyramidal zinc(II) complexes of pyridine-based ligands Dalton Transactions. pp. 3339- 3349 ,(2003) , 10.1039/B305476B
Nicole Niklas, Achim Zahl, Ralf Alsfasser, The structural mobility of zinc complexes with tetradentate tripodal ligands derived from the amino acids glycine and phenylalanine Dalton Transactions. pp. 778- 786 ,(2003) , 10.1039/B212049F
F. Ekkehardt Hahn, Christian Ochs, Thomas Lügger, Roland Fröhlich, An unsymmetrical tripodal ligand with NOS2-donor set: coordination chemistry with nickel(II) and zinc(II). Inorganic Chemistry. ,vol. 43, pp. 6101- 6107 ,(2004) , 10.1021/IC0491940
Inge I. Creaser, John D. Lydon, Alan M. Sargeson, Michael R. Snow, E. Horn, A zinc-alkyl caged cobalt(III) derivative Journal of the American Chemical Society. ,vol. 106, pp. 5729- 5731 ,(1984) , 10.1021/JA00331A054
Helen R. Bigmore, Sally C. Lawrence, Philip Mountford, Cara S. Tredget, Coordination, organometallic and related chemistry of tris(pyrazolyl)methane ligands Dalton Transactions. pp. 635- 651 ,(2005) , 10.1039/B413121E
Hongshan He, Douglas P. Linder, Kenton R. Rodgers, Indrani Chakraborty, Atta M. Arif, A thiazole-containing tripodal ligand: synthesis, characterization, and interactions with metal ions and matrix metalloproteinases. Inorganic Chemistry. ,vol. 43, pp. 2392- 2401 ,(2004) , 10.1021/IC034811Q
Bin Song, Jenny Reuber, Christian Ochs, F. Ekkehardt Hahn, Thomas Lügger, Chris Orvig, Effects of sequential replacement of -NH2 by -OH in the tripodal tetraamine tren on its acidity and metal ion coordinating properties. Inorganic Chemistry. ,vol. 40, pp. 1527- 1535 ,(2001) , 10.1021/IC0009831
Riichi Miyamoto, Ryoko Santo, Toshio Matsushita, Takanori Nishioka, Akio Ichimura, Yoshio Teki, Isamu Kinoshita, A complete series of copper(II) halide complexes (X = F, Cl, Br, I) with a novel Cu(II)-C(sp3) bond. Dalton Transactions. pp. 3179- 3186 ,(2005) , 10.1039/B507073B