Thermal and catalytic pyrolysis of vacuum gas oil using HZSM-5: TG and PY-CG/MS study
作者： Aruzza Mabel de Morais Araújo , Aneliése Lunguinho Figueiredo , Amanda Duarte Gondim , Ana Paula de Melo Alves Guedes , Luiz Di Souza
DOI: 10.1080/10916466.2015.1136947
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摘要: ABSTRACTThe zeolite HZSM-5, was synthesized in the absence of an organic template. The characterization HZSM-5 performed by X-ray diffraction, N2 adsorption/desorption isotherms and scanning electron microscopy. For catalytic tests, applying free kinetic model, it observed that activation energy for pyrolysis pure VGO 82 kJ mol−1 VGO/HZSM-5, value decreased to approximately 60 kJ mol−1, demonstrating effectiveness acid sites effect ZSM-5 resulting production gas, gasoline diesel.
sci-hub.se 参考文章(12)
S. Vyazovkin, V. Goryachko, Potentialities of software for kinetic processing of thermoanalytical data by the isoconversion method Thermochimica Acta. ,vol. 194, pp. 221- 230 ,(1992) , 10.1016/0040-6031(92)80020-W
Yuanyuan Ma, Jing Hu, Lihua Jia, Zhifang Li, Qiubin Kan, Shujie Wu, Synthesis, characterization and catalytic activity of a novel mesoporous ZSM-5 zeolite Materials Research Bulletin. ,vol. 48, pp. 1881- 1884 ,(2013) , 10.1016/J.MATERRESBULL.2013.01.014
Giuseppe Bellussi, Giacomo Rispoli, Alberto Landoni, Roberto Millini, Daniele Molinari, Erica Montanari, Daniele Moscotti, Paolo Pollesel, Hydroconversion of heavy residues in slurry reactors: Developments and perspectives Journal of Catalysis. ,vol. 308, pp. 189- 200 ,(2013) , 10.1016/J.JCAT.2013.07.002
Feng Pan, Xuchen Lu, Yun Wang, Shiwei Chen, Tizhuang Wang, Yan Yan, Organic template-free synthesis of ZSM-5 zeolite from coal-series kaolinite Materials Letters. ,vol. 115, pp. 5- 8 ,(2014) , 10.1016/J.MATLET.2013.10.007
Stephen Brunauer, P. H. Emmett, Edward Teller, Adsorption of Gases in Multimolecular Layers Journal of the American Chemical Society. ,vol. 60, pp. 309- 319 ,(1938) , 10.1021/JA01269A023
B. Saha, A.K. Maiti, A.K. Ghoshal, Model-free method for isothermal and non-isothermal decomposition kinetics analysis of PET sample Thermochimica Acta. ,vol. 444, pp. 46- 52 ,(2006) , 10.1016/J.TCA.2006.02.018
Linsheng Wang, Maosong Xie, Longxiang Tao, Conversion of light paraffins for preparing small olefins over ZSM-5 zeolites Catalysis Letters. ,vol. 28, pp. 61- 68 ,(1994) , 10.1007/BF00812470
Fernando J. Luna, Ulf Schuchardt, Modificação de zeólitas para uso em catálise Química Nova. ,vol. 24, pp. 885- 892 ,(2001) , 10.1590/S0100-40422001000600027
Shin Dong Kim, Si Hyun Noh, Jun Woo Park, Wha Jung Kim, Organic-free synthesis of ZSM-5 with narrow crystal size distribution using two-step temperature process Microporous and Mesoporous Materials. ,vol. 92, pp. 181- 188 ,(2006) , 10.1016/J.MICROMESO.2006.01.009
Paul P. Halenda, Elliott P. Barrett, Leslie G. Joyner, The Determination of Pore Volume and Area Distributions in Porous Substances ,(1951)