Synthesis, characterization and catalytic activity of a novel mesoporous ZSM-5 zeolite

作者: Yuanyuan Ma , Jing Hu , Lihua Jia , Zhifang Li , Qiubin Kan

DOI: 10.1016/J.MATERRESBULL.2013.01.014

关键词:

摘要: A novel mesoporous ZSM-5 zeolite was hydrothermally synthesized using glucose as a template. Characterizations by XRD, TEM and nitrogen isotherms indicated that possessed worm-like mesoporous. 27Al-MAS-NMR NH3-TPD showed the preserved tetrahedral coordination aluminum stronger acidity than conventional material. As-prepared successfully used in alkylation reaction of phenol with tert-butanol exhibited significantly high conversion 2,4-DTBP selectivity. In addition, hydrothermal stability also studied boiling water for 7 days displayed good results.

参考文章(23)
Avelino Corma, Maria Jose Díaz-Cabañas, Fernando Rey, Stavros Nicolopoulus, Khalid Boulahya, ITQ-15: the first ultralarge pore zeolite with a bi-directional pore system formed by intersecting 14- and 12-ring channels, and its catalytic implications. Chemical Communications. pp. 1356- 1357 ,(2004) , 10.1039/B406572G
Yousheng Tao, Hirofumi Kanoh, Katsumi Kaneko, Synthesis of mesoporous zeolite a by resorcinol-formaldehyde aerogel templating. Langmuir. ,vol. 21, pp. 504- 507 ,(2005) , 10.1021/LA047686J
Sean A. Davis, Sandra L. Burkett, Neil H. Mendelson, Stephen Mann, Bacterial templating of ordered macrostructures in silica and silica-surfactant mesophases Nature. ,vol. 385, pp. 420- 423 ,(1997) , 10.1038/385420A0
Seong-Su Kim, Jainisha Shah, Thomas J. Pinnavaia, Colloid-Imprinted Carbons as Templates for the Nanocasting Synthesis of Mesoporous ZSM-5 Zeolite Chemistry of Materials. ,vol. 15, pp. 1664- 1668 ,(2003) , 10.1021/CM021762R
Dong Ho Choi, Ji Won Park, Jong-Ho Kim, Yoshihiro Sugi, Gon Seo, Liquid-phase degradation of HDPE over alkali-treated MFI zeolites with mesopores Polymer Degradation and Stability. ,vol. 91, pp. 2860- 2866 ,(2006) , 10.1016/J.POLYMDEGRADSTAB.2006.09.002
R Giudici, H.W Kouwenhoven, R Prins, Comparison of nitric and oxalic acid in the dealumination of mordenite Applied Catalysis A-general. ,vol. 203, pp. 101- 110 ,(2000) , 10.1016/S0926-860X(00)00470-1
Claus Madsen, Claus JH Jacobsen, None, Nanosized zeolite crystals—convenient control of crystal size distribution by confined space synthesis Chemical Communications. pp. 673- 674 ,(1999) , 10.1039/A901228A
Yuanyuan Ma, Jingqi Guan, Shujie Wu, Jing Liu, Qiubin Kan, Wenxiang Zhang, Synthesis and characterization of belt-like silicalite-1 nanocrystals with mesoporous structure Materials Letters. ,vol. 64, pp. 2523- 2525 ,(2010) , 10.1016/J.MATLET.2010.08.005
C. C. Freyhardt, M. Tsapatsis, R. F. Lobo, K. J. Balkus, M. E. Davis, A high-silica zeolite with a 14-tetrahedral-atom pore opening Nature. ,vol. 381, pp. 295- 298 ,(1996) , 10.1038/381295A0
Yueqin Song, Xiangxue Zhu, Yi Song, Qingxia Wang, Longya Xu, An effective method to enhance the stability on-stream of butene aromatization: Post-treatment of ZSM-5 by alkali solution of sodium hydroxide Applied Catalysis A-general. ,vol. 302, pp. 69- 77 ,(2006) , 10.1016/J.APCATA.2005.12.023