Photolysis of Nitric Acid and Nitrate on Natural and Artificial Surfaces
作者： Chunxiang Ye , Honglian Gao , Ning Zhang , Xianliang Zhou
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摘要: Photolysis of nitric acid and nitrate (HNO3/nitrate) was investigated on the surfaces natural artificial materials, including plant leaves, metal sheets, construction materials. The were conditioned in outdoor air prior to experiments receive depositions ambient HNO3/nitrate other atmospheric constituents. photolysis rate constant (JHNO3(s)) surface measured based production rates nitrous (HONO) nitrogen oxides (NOx). JHNO3(s) values, from 6.0 × 10–6 s–1 3.7 10–4 s–1, are 1 3 orders magnitude higher than that gaseous HNO3. HONO major product most whereas NOx surfaces. values decreased with density could be described by a simple analytical equation. Within typical range low-NOx forested areas, ...
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B. Hammer, J.K. Nørskov, Theoretical surface science and catalysis—calculations and concepts Advances in Catalysis. ,vol. 45, pp. 71- 129 ,(2000) , 10.1016/S0360-0564(02)45013-4
Jennifer Schuttlefield, Gayan Rubasinghege, Mohamed El-Maazawi, Jason Bone, Vicki H. Grassian, Photochemistry of adsorbed nitrate. Journal of the American Chemical Society. ,vol. 130, pp. 12210- 12211 ,(2008) , 10.1021/JA802342M
Trevor C. VandenBoer, Cora J. Young, Ranajit K. Talukdar, Milos Z. Markovic, Steven S. Brown, James M. Roberts, Jennifer G. Murphy, Nocturnal loss and daytime source of nitrous acid through reactive uptake and displacement Nature Geoscience. ,vol. 8, pp. 55- 60 ,(2015) , 10.1038/NGEO2298
C. George, R. S. Strekowski, J. Kleffmann, K. Stemmler, M. Ammann, Photoenhanced uptake of gaseous NO2 on solid organic compounds: a photochemical source of HONO? Faraday Discussions. ,vol. 130, pp. 195- 210 ,(2005) , 10.1039/B417888M
João Victor Staub de Melo, Glicério Trichês, Philippe Jean Paul Gleize, Joe Villena, Development and evaluation of the efficiency of photocatalytic pavement blocks in the laboratory and after one year in the field Construction and Building Materials. ,vol. 37, pp. 310- 319 ,(2012) , 10.1016/J.CONBUILDMAT.2012.07.073
Juan Du, Lei Zhu, Quantification of the absorption cross sections of surface-adsorbed nitric acid in the 335–365nm region by Brewster angle cavity ring-down spectroscopy Chemical Physics Letters. ,vol. 511, pp. 213- 218 ,(2011) , 10.1016/J.CPLETT.2011.06.062
Xianliang Zhou, Honglian Gao, Yi He, Gu Huang, Steven B. Bertman, Kevin Civerolo, James Schwab, Nitric acid photolysis on surfaces in low-NOxenvironments: Significant atmospheric implications Geophysical Research Letters. ,vol. 30, pp. n/a- n/a ,(2003) , 10.1029/2003GL018620
Marja Maljanen, Pasi Yli-Pirilä, Jyrki Hytönen, Jorma Joutsensaari, Pertti J. Martikainen, Acidic northern soils as sources of atmospheric nitrous acid (HONO) Soil Biology & Biochemistry. ,vol. 67, pp. 94- 97 ,(2013) , 10.1016/J.SOILBIO.2013.08.013
N. A. Saliba, H. Yang, B. J. Finlayson-Pitts, Reaction of Gaseous Nitric Oxide with Nitric Acid on Silica Surfaces in the Presence of Water at Room Temperature Journal of Physical Chemistry A. ,vol. 105, pp. 10339- 10346 ,(2001) , 10.1021/JP012330R
Gu Huang, Xianliang Zhou, Guohong Deng, Huancheng Qiao, Kevin Civerolo, Measurements of atmospheric nitrous acid and nitric acid Atmospheric Environment. ,vol. 36, pp. 2225- 2235 ,(2002) , 10.1016/S1352-2310(02)00170-X