Biological preparation and application of poly-ferric sulfate flocculant

作者: Hui-min WANG , Xiao-bo MIN , Li-yuan CHAI , Yu-de SHU

DOI: 10.1016/S1003-6326(11)61048-0

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摘要: Abstract A novel inorganic polymer flocculant, poly-ferric sulfate (BPFS) was prepared by oxidation of ferrous using domestic Thiobacillus ferrooxidans ( T·f ) under acid condition. The optimal conditions for the preparation were pH value 1.5, (NH 4 2 SO dosage 0.5 g/L, initial Fe 2+ concentration 45g/L, inoculum 10%, rotating speed 120 r/min, reaction time 5-6 d and temperature 30 °C. Under conditions, BPFS product with 1.5-2.2, basicity 17.5%-22.7% total iron content 43.87-45.24 g/L obtained. application to three wastewaters carried out, removal efficiencies COD, decolorization Zn can be reached 70%, 90% 99%, respectively. result suggests that is an excellent flocculant water treatment.

参考文章(8)
Y. Fu, S.L. Yu, Characterization and coagulation performance of solid poly-silicic-ferric (PSF) coagulant Journal of Non-crystalline Solids. ,vol. 353, pp. 2206- 2213 ,(2007) , 10.1016/J.JNONCRYSOL.2007.02.038
Kenneth M Towe, William F Bradley, Mineralogical constitution of colloidal “hydrous ferric oxides” Journal of Colloid and Interface Science. ,vol. 24, pp. 384- 392 ,(1967) , 10.1016/0021-9797(67)90266-4
S. Hoste, L. Verdonck, G. P. van Der Kelen, IR Study on the Solid State Reaction between Iron Hydroxide and KCN Bulletin des Sociétés Chimiques Belges. ,vol. 91, pp. 597- 604 ,(2010) , 10.1002/BSCB.19820910703
I. Sondi, S. Shi, E. Matijevic´, Precipitation of monodispersed basic iron(III) sulfate (sodium jarosite) particles Colloid and Polymer Science. ,vol. 279, pp. 161- 165 ,(2001) , 10.1007/S003960000401
Anders B. Jensen, Colin Webb, Ferrous sulphate oxidation using thiobacillus ferrooxidans: a review Process Biochemistry. ,vol. 30, pp. 225- 236 ,(1995) , 10.1016/0032-9592(95)85003-1
Wilder D. Bancroft, Hydrous Ferric Oxide The Journal of Physical Chemistry. ,vol. 19, pp. 232- 240 ,(1914) , 10.1021/J150156A004