Exciton transitions in crystalline anthracene for k perpendicular to the b axis
DOI: 10.1063/1.1680638
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摘要: The energy and oscillator strength of exciton transitions with wave vector k perpendicular to the b crystal axis anthracene are calculated using second quantized boson theory compared results reflection spectroscopy. lattice sums intermolecular interactions used in calculations have a dipole component, computed Ewald's method, nondipolar higher multipole part. latter was obtained by rescaling Silbey, Rice, Jortner who Pariser wavefunctions. spectra faces (001) (201) Clark. Inclusion interaction leads substantial improvement agreement experiment. Predictions made for vectors directions parallel long (L) molecule as well another direction intermediate between normals planes.
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sci-hub.se 参考文章(30)
G.C. Morris, M.G. Sceats, Probing the non-analytic properties of exciton band structures by reflection spectroscopy Chemical Physics. ,vol. 1, pp. 259- 276 ,(1973) , 10.1016/0301-0104(73)85021-9
D P Craig, T Thirunamachandran, On multipole interaction methods in exciton theory Proceedings of the Physical Society. ,vol. 84, pp. 781- 793 ,(1964) , 10.1088/0370-1328/84/5/315
M. R. Philpott, Dipole Davydov Splittings in Crystalline Anthracene, Tetracene, Naphthalene, and Phenanthrene The Journal of Chemical Physics. ,vol. 50, pp. 5117- 5128 ,(1969) , 10.1063/1.1671026
Robert Silbey, Joshua Jortner, Stuart A. Rice, On the Singlet‐Exciton States of Crystalline Anthracene Journal of Chemical Physics. ,vol. 42, pp. 1515- 1534 ,(1965) , 10.1063/1.1696154
G. A. George, G. C. Morris, Davydov Splittings in Intense Transitions of Naphthalene and Anthracene Molecular Crystals and Liquid Crystals. ,vol. 3, pp. 397- 404 ,(1968) , 10.1080/15421406808083455
Robert M. Macnab, Kenneth Sauer, Electronic Absorption and Fluorescence Spectra of Anthracene, [D10]‐Anthracene, and Acridine in n‐Alkane Matrices at 4°K Journal of Chemical Physics. ,vol. 53, pp. 2805- 2817 ,(1970) , 10.1063/1.1674406
Max Born, Kʿun Huang, Dynamical Theory of Crystal Lattices ,(1954)
Stuart A. Rice, Graeme C. Morris, William L. Greer, Conjecture Concerning the Width of the Lowest Singlet–Singlet Transition in Crystalline Anthracene The Journal of Chemical Physics. ,vol. 52, pp. 4279- 4287 ,(1970) , 10.1063/1.1673638
H. L. Jetter, H. C. Wolf, Zur Frage der Davydov-Aufspaltung des ersten Singulett-Anregungszustandes von Anthracen-Kristallen physica status solidi (b). ,vol. 22, pp. K39- K43 ,(1967) , 10.1002/PSSB.19670220148
Leigh B. Clark, Vacuum Ultraviolet Spectra of Crystalline Anthracene The Journal of Chemical Physics. ,vol. 53, pp. 4092- 4093 ,(1970) , 10.1063/1.1673883