Fire and explosion characteristics of 3-methyl pyridine at 270°c with high oxygen concentrations
作者： R.L. Yun , T.J. Wan , C.H. Lin , Y.M. Chang , C.M. Shu
DOI: 10.1205/PSEP06055
关键词:
摘要: Abstract The mixture of 3-methyl pyridine (3-picoline) and steam is used in the production vitamin B3 gas phase. aim this study was to investigate influence inert (H2O) on flammability characteristics 3-picoline manufacturing process. Four practical vapour mixing ratios 3-picoline/steam mixtures, 5, 10, 30 100 vol% 3-picoline, were selected study. A series tests employed for determining their fire explosion characteristics. Fire H2O: 5,10, carried out a 20-L-Apparatus under simulated conditions 760 mmHg, 270°C, together with high oxygen concentrations (42 21 vol%) real experimental results showed that safety-related parameters hazard degrees all able be significantly reduced while substantial amount infused into system. While proportion up 97 vol%, would non-flammable. As result, dosing process one effective methods prevent relevant processes from incurring hazards, not mention its economical benefit.
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sci-hub.se 参考文章(16)
Tetsuya Shishido, Zhaoxia Song, Eriko Kadowaki, Ye Wang, Katsuomi Takehira, Vapor-phase oxidation of 3-picoline to nicotinic acid over Cr1-xAlxVO4 catalysts Applied Catalysis A-general. ,vol. 239, pp. 287- 296 ,(2003) , 10.1016/S0926-860X(02)00394-0
N Srinivas, M Radha Kishan, S.J Kulkarni, K.V Raghavan, Ammoxidation of picolines over modified silicoaluminophosphate molecular sieves Microporous and Mesoporous Materials. ,vol. 39, pp. 125- 134 ,(2000) , 10.1016/S1387-1811(00)00185-2
R. Ramachandra Rao, S.J. Kulkarni, M. Subrahmanyam, A.V. Rama Rao, Ammoxidation of 3-picoline over vanadium-modified zeolites and crystalline/amorphous silicoaluminophosphate catalysts Zeolites. ,vol. 16, pp. 254- 257 ,(1996) , 10.1016/0144-2449(95)00144-1
K.V. Narayana, B. David Raju, S. Khaja Masthan, V. Venkat Rao, P. Kanta Rao, A. Martin, Cerium fluoride supported V2O5 catalysts: physico-chemical characterization and 3-picoline ammoxidation activity Journal of Molecular Catalysis A-chemical. ,vol. 223, pp. 321- 328 ,(2004) , 10.1016/J.MOLCATA.2004.02.033
M. Vidal, W.J. Rogers, M.S. Mannan, Prediction of Minimum Flash Point Behaviour for Binary Mixtures Process Safety and Environmental Protection. ,vol. 84, pp. 1- 9 ,(2006) , 10.1205/PSEP.05041
Chi-Min Shu, Po-Jiun Wen, Investigation of the flammability zone of o-xylene under various pressures and oxygen concentrations at 150 °C Journal of Loss Prevention in The Process Industries. ,vol. 15, pp. 253- 263 ,(2002) , 10.1016/S0950-4230(02)00016-5
A.A. Pekalski, J.F. Zevenbergen, S.M. Lemkowitz, H.J. Pasman, A review of explosion prevention and protection systems suitable as ultimate layer of protection in chemical process installations Process Safety and Environmental Protection. ,vol. 83, pp. 1- 17 ,(2005) , 10.1205/PSEP.04023
Y M Chang, K H Hu, J K Chen, C M Shu, Flammability studies of benzene and methanol with different vapor mixing ratios under various initial conditions Journal of Thermal Analysis and Calorimetry. ,vol. 83, pp. 107- 112 ,(2006) , 10.1007/S10973-005-7062-4
K.V. Narayana, S. Khaja Masthan, V. Venkat Rao, B. David Raju, P. Kanta Rao, Influence of V2O5 content on ammoxidation of 3-picoline over V2O5/AlF3 catalysts Catalysis Communications. ,vol. 3, pp. 173- 178 ,(2002) , 10.1016/S1566-7367(02)00072-9
M. Anderson, Behavioural Safety and Major Accident Hazards: Magic Bullet or Shot in the Dark? Process Safety and Environmental Protection. ,vol. 83, pp. 109- 116 ,(2005) , 10.1205/PSEP.04230