Optimal geometry parameter for plasmonic sensitivities of individual Au nanopoarticle sensors

作者: ChaoLing Du , WanChun Yang , Sheng Peng , DaNing Shi

DOI: 10.1039/C9CP00309F

关键词:

摘要: The shape, aspect ratio and size are key parameters governing the plasmon sensitivities of individual Au nanoparticle bio/chemical sensors. It is crucial to unveil general geometry optimize their corresponding sensitivity applications. In this work, geometry-dependent refractive-index factor (S) figure merit (FOM) sensors (including a nanodisc, nanorod, nanoellipsoid hexagonal nanoplate) numerically investigated by discrete dipole approximation (DDA). S revealed increase quadratically/linearly with ratio, while FOM reaches maximum at an optimized about 3.0/8.0 for studied prolate/oblate nanoparticles, respectively, reflecting shapes ratios and, hence, effects. However, responses shape factors shown follow nearly same trend regardless different detailed geometries, demonstrating that provide concerned This can be analytically explained well under dipolar localized surface resonance (LSPR) conditions. Their optimal predicted 12.5 RIU−1 10.5; underlying reason discussed as well. obtained results in work believed hold great promise choosing appropriate LSPR-based sensor design applications access simultaneously.

参考文章(37)
Yuhua Feng, Yawen Wang, Jiating He, Xiaohui Song, Yee Yan Tay, Huey Hoon Hng, Xing Yi Ling, Hongyu Chen, Achieving Site-Specificity in Multistep Colloidal Synthesis. Journal of the American Chemical Society. ,vol. 137, pp. 7624- 7627 ,(2015) , 10.1021/JACS.5B04310
Craig F. Bohren, Donald R. Huffman, Absorption and Scattering of Light by Small Particles ,(1983)
Jill E. Millstone, Wei Wei, Matthew R. Jones, Hyojong Yoo, Chad A. Mirkin, Halide ion control of seed mediated growth of anisotropic gold nanoparticles Nano Letters. ,vol. 8, pp. 2526- 2529 ,(2009) , 10.1021/NL8016253
Paerhatijiang Tuersun, Xiang'e Han, Optimal dimensions of gold nanoshells for light backscattering and absorption based applications Journal of Quantitative Spectroscopy & Radiative Transfer. ,vol. 146, pp. 468- 474 ,(2014) , 10.1016/J.JQSRT.2013.12.018
Jie Cao, Tong Sun, Kenneth T.V. Grattan, Gold nanorod-based localized surface plasmon resonance biosensors: A review Sensors and Actuators B-chemical. ,vol. 195, pp. 332- 351 ,(2014) , 10.1016/J.SNB.2014.01.056
Jie Cao, Minh Hieu Tu, Tong Sun, Kenneth T.V. Grattan, Wavelength-based localized surface plasmon resonance optical fiber biosensor Sensors and Actuators B-chemical. ,vol. 181, pp. 611- 619 ,(2013) , 10.1016/J.SNB.2013.02.052
Carsten Sönnichsen, Björn M Reinhard, Jan Liphardt, A Paul Alivisatos, A molecular ruler based on plasmon coupling of single gold and silver nanoparticles. Nature Biotechnology. ,vol. 23, pp. 741- 745 ,(2005) , 10.1038/NBT1100
B. T. Draine, Jeremy Goodman, Beyond Clausius-Mossotti - Wave propagation on a polarizable point lattice and the discrete dipole approximation The Astrophysical Journal. ,vol. 405, pp. 685- 697 ,(1993) , 10.1086/172396
Marinus A Otte, Borja Sepulveda, Weihai Ni, Jorge Pérez Juste, Luis M Liz-Marzán, Laura M Lechuga, None, Identification of the optimal spectral region for plasmonic and nanoplasmonic sensing. ACS Nano. ,vol. 4, pp. 349- 357 ,(2010) , 10.1021/NN901024E