Chemical oxidation as repairing technique to restore corrosion resistance on damaged anodized titanium

作者: Davide Prando , Davide Nicolis , Fabio Bolzoni , MariaPia Pedeferri , Marco Ormellese

DOI: 10.1016/J.SURFCOAT.2019.03.005

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摘要: Abstract Anodized titanium shows an excellent resistance to pitting corrosion. However, it could be subject failure in case of local removal the oxide film due, for example, incorrect handling during transport, installation, or use. Depending on part size and usage, electrochemical anodizing treatment not feasible. In this case, localized chemical oxidation used recover damaged restore corrosion resistance. Chemical was performed by immersion NaOH 10 M H2O2 at temperature from room 90 °C with duration ranging between 1 h 72 h. Potentiodynamic tests bromides 0.5 M were determine effectiveness relation one obtained anodic oxidation. Higher bath led faster growth film, however has no effect final Breakdown potential increased duration. The establishment a plateau occurs earlier stage, as is increased. Titanium samples anodized then scratched, simulate mechanical removal, recovered using initial restored. suggested treatments in-situ recovery are 72 h exposure 6 h temperature.

参考文章(31)
Christina Kim, Matthew R Kendall, Matthew A Miller, Courtney L Long, Preston R Larson, Mary Beth Humphrey, Andrew S Madden, A Cuneyt Tas, None, Comparison of titanium soaked in 5 M NaOH or 5 M KOH solutions. Materials Science and Engineering: C. ,vol. 33, pp. 327- 339 ,(2013) , 10.1016/J.MSEC.2012.08.047
Pentti Tengvall, Hans Elwing, Lars Sjöqvist, Ingemar Lundström, Lars Magnus Bjursten, Interaction between hydrogen peroxide and titanium: a possible role in the biocompatibility of titanium. Biomaterials. ,vol. 10, pp. 118- 120 ,(1989) , 10.1016/0142-9612(89)90043-4
I.V Gorynin, Titanium alloys for marine application Materials Science and Engineering A-structural Materials Properties Microstructure and Processing. ,vol. 263, pp. 112- 116 ,(1999) , 10.1016/S0921-5093(98)01180-0
Sungmo Moon, Chanyoung Jeong, Eungsun Byon, Yongsoo Jeong, Electrochemical Behavior of Titanium in NaOH Solutions 208th ECS Meeting. ,vol. 1, pp. 151- 156 ,(2006) , 10.1149/1.2215498
S. Sathish, M. Geetha, N.D. Pandey, C. Richard, R. Asokamani, Studies on the corrosion and wear behavior of the laser nitrided biomedical titanium and its alloys Materials Science and Engineering: C. ,vol. 30, pp. 376- 382 ,(2010) , 10.1016/J.MSEC.2009.12.004
JOHN C. GRIESS, Crevice Corrosion of Titanium in Aqueous Salt Solutions Corrosion. ,vol. 24, pp. 96- 109 ,(1968) , 10.5006/0010-9312-24.4.96
Sannakaisa Virtanen, Corrosion of Biomedical Implant Materials Corrosion Reviews. ,vol. 26, pp. 147- 171 ,(2008) , 10.1515/CORRREV.2008.147
J.A. Richardson, Corrosion in Alkalis Reference Module in Materials Science and Materials Engineering#R##N#Shreir's Corrosion. ,vol. 2, pp. 1191- 1206 ,(2010) , 10.1016/B978-044452787-5.00195-5
Davide Prando, Andrea Brenna, Fabio M. Bolzoni, Maria V. Diamanti, Mariapia Pedeferri, Marco Ormellese, Electrochemical anodizing treatment to enhance localized corrosion resistance of pure titanium. Journal of Applied Biomaterials & Functional Materials. ,vol. 15, pp. 19- 24 ,(2017) , 10.5301/JABFM.5000344
Akram Alfantazi, Edouard Asselin, Jing Liu, The Pitting Corrosion of Titanium in Aggressive Environments: A Review Corrosion. ,(2016)