Synthesis and crystal structures of cobalt(III) and zinc(II) complexes with Schiff bases
作者： Z Hong , CL Du , YP Yu , None
DOI: 10.1134/S1070328411040051
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摘要: Two new cobalt(III) and zinc(II) complexes, [Co(L1)2 (H2O)] · ClO4 (I) [Ni(L2)2 (H2O)2] 2ClO4 (II), where L1 is the deprotonated form of 5-methoxy-2-[(2-morpholin-4-ylethylimino)methyl]phenol, L2 zwitterionic 2-[(2-isopropylaminoethylimino)methyl]-5-methoxyphenol, were synthesized structurally characterized by elemental analyses, IR spectra, single-crystal X-ray diffraction. The crystal I monoclinic: space group P21/c, a = 11.1512(4), b 28.2424(11), c 10.9655(4) A, β 95.746(2)°, V 3436.1(2) A3, Z 4. II triclinic: 8.1441(2), 10.4531(3), 10.8849(3) α 84.0240(10)°, 76.9800(10)°, γ 74.2280(10)°, 867.92(4) 1. Complex consists mononuclear complex cation perchlorate anion. crystallographic centrosymmetric nickel(II) two anions. Each metal atom in complexes an octahedral coordination.
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