作者: G.V. Gusakova , A.L. Smolyanskii
DOI: 10.1016/0032-3950(88)90193-1
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摘要: The results of IR spectroscopic investigations the formation and rupture hydrogen bonds intermolecular proton transfer in complexes involving carboxyl groups polymeric matrices have been generalized. Most attention has given to consideration effect molecular mobility polymers on thermodynamic condition system bonds. Deviation bond proton-transfer complex from equilibrium state occurs at temperatures corresponding characteristic relaxation transitions matrix.