Micromechanical properties of random copolymers of styrene with methacrylic acid. experimental and theoretical approaches

作者: A. Bergeret , A. Agbossou , N. Alberola , P. Cassagnau , T. Sarraf

DOI: 10.1016/0014-3057(92)90207-I

关键词:

摘要: Abstract Styrene-(methacrylic acid) random copolymers with various contents of methacrylic acid were studied by dynamic mechanical spectroscopy. From experimental data obtained under isothermal conditions, a physical model behaviour near Tg such was established. Such theoretical approach quantitatively points out changes in molecular motion macromolecular chains brought about acid. these results, it concluded that hydrogen bondings between segments, induced the presence acid, could act as ties network.

参考文章(14)
JY Cavaille, J Perez, GP Johari, None, Molecular theory for the rheology of glasses and polymers. Physical Review B. ,vol. 39, pp. 2411- 2422 ,(1989) , 10.1103/PHYSREVB.39.2411
V.A. Bershtein, M.Z. Petkevich, L.G. Razgulyayeva, V.A. Stepanov, The temperature dependence of intermolecular interaction in polymers in the glassy state Polymer Science U.S.S.R.. ,vol. 20, pp. 3005- 3013 ,(1978) , 10.1016/0032-3950(78)90514-2
G. R. Brannock, J. W. Barlow, D. R. Paul, Blends of styrene/acrylic acid copolymers and acrylic polymers Journal of Polymer Science Part B: Polymer Physics. ,vol. 28, pp. 871- 891 ,(1990) , 10.1002/POLB.1990.090280606
V. Frosini, A. E. Woodward, Effects of orientation on dynamic shear behavior of some amorphous polymers from 4.2° to 300°K Journal of Polymer Science Part A-2: Polymer Physics. ,vol. 7, pp. 525- 536 ,(1969) , 10.1002/POL.1969.160070307
Mario Baccaredda, Enzo Butta, Vittorio Frosini, Molecular motions and mechanical relaxation effects in atactic and isotactic polystyrenes at very low temperatures Journal of Polymer Science Part B: Polymer Letters. ,vol. 3, pp. 189- 194 ,(1965) , 10.1002/POL.1965.110030307
G.V. Gusakova, A.L. Smolyanskii, Molecular dynamics in polymers and the hydrogen bond Polymer Science U.S.S.R.. ,vol. 30, pp. 809- 818 ,(1988) , 10.1016/0032-3950(88)90193-1
C Jourdan, JY Cavaille, J Perez, None, Mechanical relaxations in polypropylene: A new experimental and theoretical approach Journal of Polymer Science Part B: Polymer Physics. ,vol. 27, pp. 2361- 2384 ,(1989) , 10.1002/POLB.1989.090271115
JY Cavaille, Corinne Jourdan, J Perez, L Monnerie, GP Johari, None, Time-temperature superposition and dynamic mechanical behavior of atactic polystyrene Journal of Polymer Science Part B: Polymer Physics. ,vol. 25, pp. 1235- 1251 ,(1987) , 10.1002/POLB.1987.090250605