Continuous microfluidic fabrication of polypyrrole nanoparticles
作者： Elham Effati , Behzad Pourabbas , Mohammad Sadegh Zakerhamidi
DOI: 10.1039/C9RA00946A
关键词:
摘要: Polypyrrole (PPy) nanoparticles were synthesized successfully by oxidation polymerization in droplets microfluidic system. The oxidizing agent ammonium persulfate was added at various molar ratios with respect to the monomer. details of procedure, droplet formation inside channel and effects factors are described. method is a fast continuous way for synthesis PPy. Products characterized using Fourier-transform infrared spectroscopy, field emission scanning electron microscopy, transmission X-ray diffraction, thermal gravimetric analysis, cyclic voltammetry, electrochemical impedance spectroscopy photoluminescence spectroscopy.
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sci-hub.se 参考文章(35)
A.T. Mane, S.T. Navale, R.S. Mane, Mu. Naushad, V.B. Patil, Synthesis and structural, morphological, compositional, optical and electrical properties of DBSA-doped PPy–WO3 nanocomposites Progress in Organic Coatings. ,vol. 87, pp. 88- 94 ,(2015) , 10.1016/J.PORGCOAT.2015.05.007
Aijian Wang, Wei Zhao, Wang Yu, Effect of acid/base on the third-order optical nonlinearity of polypyrrole Journal of Molecular Structure. ,vol. 1099, pp. 291- 296 ,(2015) , 10.1016/J.MOLSTRUC.2015.06.073
Jana Tabačiarová, Matej Mičušík, Pavol Fedorko, Mária Omastová, Study of polypyrrole aging by XPS, FTIR and conductivity measurements Polymer Degradation and Stability. ,vol. 120, pp. 392- 401 ,(2015) , 10.1016/J.POLYMDEGRADSTAB.2015.07.021
Microfluidic Production of Hydrogel Particles Microfluidic Reactors for Polymer Particles. pp. 146- 169 ,(2011) , 10.1002/9780470979228.CH8
Microfluidic Synthesis of Polymer Particles with Non‐Conventional Shapes Microfluidic Reactors for Polymer Particles. pp. 192- 214 ,(2011) , 10.1002/9780470979228.CH10
Synthesis of Polymer Particles in Microfluidic Reactors John Wiley & Sons, Ltd. pp. 109- 145 ,(2011) , 10.1002/9780470979228.CH7
György Inzelt, Conducting Polymers Monographs in Electrochemistry. ,(2012) , 10.1007/978-3-642-27621-7
Maria Grzeszczuk, Grażyna Żabińska-Olszak, Effects of the secondary counterions in the electrochemistry of polypyrrole Journal of Electroanalytical Chemistry. ,vol. 427, pp. 169- 177 ,(1997) , 10.1016/S0022-0728(96)05002-4
Wanqin Wang, Demei Yu, Feng Tian, Photoluminescence of a soluble polypyrrole based on N-vinylpyrrole Journal of Luminescence. ,vol. 130, pp. 494- 497 ,(2010) , 10.1016/J.JLUMIN.2009.10.020
K. Keiji Kanazawa, A. F. Diaz, Roy H. Geiss, William D. Gill, James F. Kwak, J. Anthony Logan, John F. Rabolt, G. Bryan Street, ‘Organic metals’: polypyrrole, a stable synthetic ‘metallic’ polymer Journal of The Chemical Society, Chemical Communications. pp. 854- 855 ,(1979) , 10.1039/C39790000854