Nucleotide Torsional Flexibility in Solution and the Use of the Lanthanides as Nuclear‐Magnetic‐Resonance Conformational Probes
作者： Carlos F. G. C. GERALDES , Robert J. P. WILLIAMS
DOI: 10.1111/J.1432-1033.1978.TB12261.X
关键词:
摘要: In this article the single family of conformations adenosine 5′-monophosphate (5′AMP) in aqueous solution previously obtained using lanthanide ions as nuclear magnetic resonance (NMR) probes is shown to disagree with conformational data available from independent NMR methods, such coupling constants and Overhauser enhancement analysis. The original experimental reinterpreted assuming contribution different conformers observed perturbations. average conformation for 5′ AMP agrees quite satisfactorily other information.
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