Metal–Organic Frameworks: Frameworks Containing Open Sites
作者： Yabing He , Banglin Chen
DOI: 10.1002/9781119951438.EIBC2213
关键词:
摘要: Open metal site (OMS)s, also referred to as coordinatively unsaturated metals, play very important roles in their specific recognition of small molecules. In this chapter, we have outlined different strategies create OMSs on the pore surfaces metal–organic frameworks (MOFs), and potential applications porous MOFs with storage energy carrier gases (e.g., hydrogen, methane, acetylene), gas separation (postcombustion CO2 capture, light hydrocarbon separation, purification chemical sensing, heterogeneous catalysis. Keywords: metal–organic frameworks; open sites; gas storage; CO2 capture; light hydrocarbons; chemical sensing; catalysis
sci-hub.se 参考文章(103)
Vanessa K. Peterson, Yun Liu, Craig M. Brown, Cameron J. Kepert, Neutron Powder Diffraction Study of D2 Sorption in Cu3(1,3,5-benzenetricarboxylate)2 Journal of the American Chemical Society. ,vol. 128, pp. 15578- 15579 ,(2006) , 10.1021/JA0660857
Zhangjing Zhang, Shengchang Xiang, Xingtang Rao, Qian Zheng, Frank R. Fronczek, Guodong Qian, Banglin Chen, A rod packing microporous metal–organic framework with open metal sites for selective guest sorption and sensing of nitrobenzene Chemical Communications. ,vol. 46, pp. 7205- 7207 ,(2010) , 10.1039/C0CC01236J
Yong Yan, Irvin Telepeni, Sihai Yang, Xiang Lin, Winfried Kockelmann, Anne Dailly, Alexander J. Blake, William Lewis, Gavin S. Walker, David R. Allan, Sarah A. Barnett, Neil R. Champness, Martin Schröder, Metal−Organic Polyhedral Frameworks: High H2 Adsorption Capacities and Neutron Powder Diffraction Studies Journal of the American Chemical Society. ,vol. 132, pp. 4092- 4094 ,(2010) , 10.1021/JA1001407
Owen R. Evans, Helen L. Ngo, Wenbin Lin, Chiral Porous Solids Based on Lamellar Lanthanide Phosphonates Journal of the American Chemical Society. ,vol. 123, pp. 10395- 10396 ,(2001) , 10.1021/JA0163772
Hui Xu, Yabing He, Zhangjing Zhang, Shengchang Xiang, Jianfeng Cai, Yuanjing Cui, Yu Yang, Guodong Qian, Banglin Chen, A microporous metal–organic framework with both open metal and Lewis basic pyridyl sites for highly selective C2H2/CH4 and C2H2/CO2 gas separation at room temperature Journal of Materials Chemistry. ,vol. 1, pp. 77- 81 ,(2013) , 10.1039/C2TA00155A
Wei Zhou, Jose M. Gallegos, Yun Liu, Banglin Chen, Shengchang Xiang, Exceptionally High Acetylene Uptake in a Microporous Metal−Organic Framework with Open Metal Sites Journal of the American Chemical Society. ,vol. 131, pp. 12415- 12419 ,(2009) , 10.1021/JA904782H
Stephen S-Y Chui, Samuel M-F Lo, Jonathan PH Charmant, A Guy Orpen, Ian D Williams, A chemically functionalizable nanoporous material (Cu3(TMA)2(H2O)3)n Science. ,vol. 283, pp. 1148- 1150 ,(1999) , 10.1126/SCIENCE.283.5405.1148
Zhiyong Guo, Hui Xu, Shengqun Su, Jianfeng Cai, Song Dang, Shengchang Xiang, Guodong Qian, Hongjie Zhang, Michael O’Keeffe, Banglin Chen, A robust near infrared luminescent ytterbium metal–organic framework for sensing of small molecules Chemical Communications. ,vol. 47, pp. 5551- 5553 ,(2011) , 10.1039/C1CC10897B
Qing Min Wang, Dongmin Shen, Martin Bülow, Miu Ling Lau, Shuguang Deng, Frank R Fitch, Norberto O Lemcoff, Jessica Semanscin, Metallo-organic molecular sieve for gas separation and purification Microporous and Mesoporous Materials. ,vol. 55, pp. 217- 230 ,(2002) , 10.1016/S1387-1811(02)00405-5
Mitsuru Kondo, Tomomichi Yoshitomi, Hiroyuki Matsuzaka, Susumu Kitagawa, Kenji Seki, Three‐Dimensional Framework with Channeling Cavities for Small Molecules: {[M2(4, 4′‐bpy)3(NO3)4]·xH2O}n (M Co, Ni, Zn) Angewandte Chemie. ,vol. 36, pp. 1725- 1727 ,(1997) , 10.1002/ANIE.199717251