High-Temperature High-Pressure Synthesis of the Highly Condensed Nitridophosphates NaP4N7, KP4N7, RbP4N7, and CsP4N7 and Their Crystal-Structure Determinations by X-ray Powder Diffraction
作者： Kai Landskron , Elisabeth Irran , Wolfgang Schnick
DOI: 10.1002/(SICI)1521-3765(19990903)5:9<2548::AID-CHEM2548>3.0.CO;2-W
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摘要: Novel highly condensed nitridophosphates MP4N7 have been obtained by the reaction of respective azides MN3 (M = Na, K, Rb, or Cs) with P3N5 under high-temperature high-pressure conditions in a belt apparatus (structure NaP4N7 depicted). Under normal pressure as well decompose above 900 °C evolution N2. However these specific thermal stability PN compounds has raised more than 1000 °C, thus yielding good crystallization products.
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