(H3O)2NaAl3F12, isostructural with A2NaAl3F12 (A = K(+), Rb(+), Cs(+)) fluorides having HTB-type sheets.
作者： Laurent Jouffret , Jerome Lhoste , Annie Hemon-Ribaud , Marc Leblanc , Vincent Maisonneuve
DOI: 10.1107/S205322961400919X
关键词:
摘要: The title compound, (H3O)2NaAl3F12 [dihydronium sodium trialuminum(III) dodecafluoride], was obtained by solvothermal synthesis from the reaction of aluminium hydroxide, 1,2,4-triazole and aqueous HF in ethanol at 463 K for 48 h. structure consists AlF6 octahedra organized [AlF4(-)]n HTB-type sheets (HTB is hexagonal tungsten bronze) separated H3O(+) Na(+) cations.
sci-hub.se 参考文章(25)
Markus M�ller, Bernd G. M�ller, Cs2Cu3MIVF12 (MIV = Zr, Hf) – Kristallstruktur und magnetische Eigenschaften Zeitschrift für anorganische und allgemeine Chemie. ,vol. 621, pp. 993- 1000 ,(1995) , 10.1002/ZAAC.19956210617
Alexandre Vimont, Jean-Claude Lavalley, Loïc Francke, Alain Demourgues, Alain Tressaud, Marco Daturi, Infrared study of the surface properties of HTB-type Al-, Cr-, Fe-hydroxyfluorides Journal of Physical Chemistry B. ,vol. 108, pp. 3246- 3255 ,(2004) , 10.1021/JP036496Z
M. Leblanc, G. Ferey, Y. Calage, R. De Pape, Idle spin behavior of the shifted hexagonal tungsten bronze type compounds FeIIFeIII2F8(H2O)2 and MnFe2F8(H2O)2 Journal of Solid State Chemistry. ,vol. 53, pp. 360- 368 ,(1984) , 10.1016/0022-4596(84)90113-0
C. Jacoboni, A. Leble, J.J. Rousseau, De´termination pre´cise de la structure de la chiolite Na5Al3F14 ete´tude par R.P.E. de Na5Al3F14:Cr3+ Journal of Solid State Chemistry. ,vol. 36, pp. 297- 304 ,(1981) , 10.1016/0022-4596(81)90440-0
M. Leblanc, G. Ferey, P. Chevallier, Y. Calage, R. De Pape, Hexagonal tungsten bronze-type FeIII fluoride: (H2O)0.33FeF3; crystal structure, magnetic properties, dehydration to a new form of iron trifluoride Journal of Solid State Chemistry. ,vol. 47, pp. 53- 58 ,(1983) , 10.1016/0022-4596(83)90041-5
Louis J. Farrugia, WinGX and ORTEP for Windows: an update Journal of Applied Crystallography. ,vol. 45, pp. 849- 854 ,(2012) , 10.1107/S0021889812029111
A. Le Bail, Y. Gao, J.L. Fourquet, C. Jacoboni, Structure determination of A2NaAl3F12 (A=K, Rb) Materials Research Bulletin. ,vol. 25, pp. 831- 839 ,(1990) , 10.1016/0025-5408(90)90059-B
K. Matan, T. Ono, Y. Fukumoto, T. J. Sato, J. Yamaura, M. Yano, K. Morita, H. Tanaka, Pinwheel valence-bond solid and triplet excitations in the two-dimensional deformed kagome lattice Nature Physics. ,vol. 6, pp. 865- 869 ,(2010) , 10.1038/NPHYS1761
G. Courbion, C. Jacoboni, R. de Pape, La structure cristalline de Cs2NaAl3F12 Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 32, pp. 3190- 3193 ,(1976) , 10.1107/S0567740876009928
Damien Dambournet, Alain Demourgues, Charlotte Martineau, Stanislas Pechev, Jérôme Lhoste, Jérôme Majimel, Alexandre Vimont, Jean-Claude Lavalley, Christophe Legein, Jean-Yves Buzaré, Franck Fayon, Alain Tressaud, Nanostructured Aluminium Hydroxyfluorides Derived from β-AlF3 Chemistry of Materials. ,vol. 20, pp. 1459- 1469 ,(2008) , 10.1021/CM702603B