A hydrogen bond scaffold supported synthetic heme FeIII–O2− adduct

作者: Kaustuv Mittra , Sudipta Chatterjee , Subhra Samanta , Kushal Sengupta , Hridaynath Bhattacharjee

DOI: 10.1039/C2CC35162E

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摘要: A hydrogen bonded heme-FeIII–O2− adduct is stabilized and characterized using resonance Raman EPR spectroscopy. The low O–O vibrations of this complex are quite different from those reported for other adducts.

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