Modeling of the thermal n-octane oxidation in the liquid phase

摘要: Thermal n-octane oxidation in the liquid phase is studied. Molecular schemes of reactions with two possibilities kinetic equations used for lumping compounds are tested. Parameters calculated by a multiresponse linear method, and discrimination among models carried out applying both statistical physical criteria. The production rate distribution products interest, such as ketones, alcohols, acids, described, after relationships parameters temperature oxygen partial pressure established nonlinear regression.