Aziridination of alkenes using 3-acetoxyaminoquinazolin-4-(3H)ones in the presence of tertiary amines: evidence for an azaimide (N-nitrene) intermediate

作者: Robert S. Atkinson , Emma Barker

DOI: 10.1039/C39950000819

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摘要: Solutions of the triethylammonium imide 8, formed from triethylamine and 3-acetoxyaminoquinazolinone 4, react with alkenes at –30 °C to give aziridines; reactivity aziridinating intermediate is consistent its formulation as an azaimide (N-nitrene).

参考文章(2)
Robert S. Atkinson, Michael J. Grimshire, Brian J. Kelly, Aziridination by oxidative addition of -aminoquinazolones to alkenes: Evidence for non-involvement of -nitrenes Tetrahedron. ,vol. 45, pp. 2875- 2886 ,(1989) , 10.1016/S0040-4020(01)80116-2
Waldemar Adam, Bernd Nestler, Hydroxy-directed regio-diastereoselective ene reaction of singlet oxygen with chiral allylic alcohols Journal of the American Chemical Society. ,vol. 115, pp. 5041- 5049 ,(1993) , 10.1021/JA00065A013