Degradation of azurite in mural paintings: distribution of copper carbonate, chlorides and oxalates by SRFTIR

作者: A. Lluveras , S. Boularand , A. Andreotti , M. Vendrell-Saz

DOI: 10.1007/S00339-010-5673-5

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摘要: This article illustrates the analysis by synchrotron micro-analytical techniques of an azurite painting presenting greenish chromatic degradation. The challenge experiments was to obtain spatial distribution degradation products azurite. Copper hydroxychlorides, carbonates and copper oxalates have been mapped SR FTIR imaging cross sections in transmission mode. To complement information, Py/GC/MS GC/MS were applied order characterize binding media organic materials present as well their products. Results contribute a better understanding decay blue areas ancient paintings not only from particular point view weathering, but also adding information regarding oxalates’ formation samples. Synchrotron radiation demonstrates its capability for mapping sections.

参考文章(27)
Vitruvio, José Luis Oliver Domingo, Los diez libros de arquitectura Alianza Editorial. ,(1997)
J Madejová, FTIR techniques in clay mineral studies Vibrational Spectroscopy. ,vol. 31, pp. 1- 10 ,(2003) , 10.1016/S0924-2031(02)00065-6
María C. D’Antonio, Daniel Palacios, Liliana Coggiola, Enrique J. Baran, Vibrational and electronic spectra of synthetic moolooite. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 68, pp. 424- 426 ,(2007) , 10.1016/J.SAA.2006.11.054
Alan Phenix, Ashok Roy, Artists' Pigments: A Handbook of Their History and Characteristics, Volume 2 Studies in Conservation. ,vol. 40, pp. 68- ,(1995) , 10.2307/1506614
E. Abelev, N. Sezin, Y. Ein-Eli, An alternative isolation of tungsten tips for a scanning tunneling microscope Review of Scientific Instruments. ,vol. 76, pp. 106105- ,(2005) , 10.1063/1.2075187
Martin V. Dutton, Christine S. Evans, Oxalate production by fungi : its role in pathogenicity and ecology in the soil environment Canadian Journal of Microbiology. ,vol. 42, pp. 881- 895 ,(1996) , 10.1139/M96-114
Peter Vandenabeele, Karel Lambert, Sofie Matthys, Walter Schudel, Anna Bergmans, Luc Moens, In situ analysis of mediaeval wall paintings: a challenge for mobile Raman spectroscopy Analytical and Bioanalytical Chemistry. ,vol. 383, pp. 707- 712 ,(2005) , 10.1007/S00216-005-0045-2
A. Lluveras, S. Boularand, J. Roqué, M. Cotte, P. Giráldez, M. Vendrell-Saz, Weathering of gilding decorations investigated by SR: development and distribution of calcium oxalates in the case of Sant Benet de Bages (Barcelona, Spain) Applied Physics A. ,vol. 90, pp. 23- 33 ,(2007) , 10.1007/S00339-007-4228-X