Metal-free α-CH amination of ethers with hypervalent sulfonylimino-λ3-bromane that acts as an active nitrenoid.
作者： Masahito Ochiai , Shinichi Yamane , Md. Mahbubul Hoque , Motomichi Saito , Kazunori Miyamoto
DOI: 10.1039/C2CC31523H
关键词:
摘要: Hypervalent N-triflylimino-λ3-bromane undergoes direct and regioselective α-C–H amination of ethers at room temperature under transition metal-free conditions. Kinetic results, …
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