Preparation, etude structurale et vibrationnelle des complexes M2U2O5Cl4, 2H2O (M = Rb, Cs): Mise en evidence d'un anion tetranucleaire |(UO2)4O2Cl8(H2O)2|4−
作者： A. Perrin
DOI: 10.1016/0022-1902(77)80339-4
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摘要: Abstract The interaction between M 2 UO Cl 4 , n H O (M = Rb, Cs) and (OH) leads to new complexes U 5 2H O: however, structural determination by X-ray diffraction exhibits discrete tetranuclear anions |(UO ) 8 (H O) | 4− : uranyl groups are bonded together in their equatorial plane O/O or O/Cl double br which oxygen atom is tricoordinated with UO (bridge) distances lying 2,20 2,29 A. Vibrational spectra recorded interpreted hydrogen bonds discussed.
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