Complexation of a hexameric uranium(VI) cluster by p-benzylcalix[7]arene
作者： Pierre Thuéry, , Martine Nierlich , Bahari Souley , Zouhair Asfari , Jacques Vicens
DOI: 10.1039/A903289D
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摘要: The reaction of uranyl nitrate hexahydrate with p-benzylcalix[7]arene (H7L) in the presence 1,4-diazabicyclo[2.2.2]octane (DABCO) resulted formation compound (UO22+)6(L7–)2(O2–)2(HDABCO+)6·3CH3CN· CHCl3·5CH3OH·3H2O 1, whose crystal structure has been determined. In symmetry-centred complex core a hexanuclear uranium(VI) cluster is surrounded by two calixarene units. Each calixarene, conformation different from usual one, encompasses UO22+ moieties, which are bonded to three or four phenolic oxygen atoms and also one other their atoms. ions located between moieties involved, together former ions, pseudo-trigonal µ3-oxo-centred assemblies. This complex, represents largest metal ion assemblies chemistry, illustrates ‘cluster keeper’ character larger calixarenes.
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sci-hub.se 参考文章(13)
Pekka Pyykko, Liisa J. Laakkonen, Kazuyuki Tatsumi, REX calculations. 12. Iteration parameters for the 5f-element organometallics of thorium-neptunium. Geometries of thorium dioxide and uranyl ion revisited Inorganic Chemistry. ,vol. 28, pp. 1801- 1805 ,(1989) , 10.1021/IC00309A009
Zbyszek Otwinowski, Wladek Minor, Processing of X-ray diffraction data collected in oscillation mode Methods in Enzymology. ,vol. 276, pp. 307- 326 ,(1997) , 10.1016/S0076-6879(97)76066-X
David M. Barnhart, Carol J. Burns, Nancy N. Sauer, John G. Watkin, Synthesis of Neutral and Anionic Uranyl Aryloxide Complexes from Uranyl Amide Precursors: X-ray Crystal Structures of UO2(O-2,6-i-Pr2C6H3)2(py)3 and [Na(THF)3]2[UO2(O-2,6-Me2C6H3)4] Inorganic Chemistry. ,vol. 34, pp. 4079- 4084 ,(1995) , 10.1021/IC00120A011
David Rose, Yuan-Da Chang, Qin Chen, Jon Zubieta, Reactions of Uranyl Thiolate Complexes with Molecular Oxygen: Syntheses and Crystal and Molecular Structures of the Uranyl Thiolate Peroxo Species (HNEt3)2[(UO2)2(O2)(SC4N2H3)4] and (HNEt3)[H(UO2)2(O2)(SC4N2H2Me)4].cntdot.Me2CO.cntdot.0.5Et3N and of the Uranyl Thiolate Oxo Cluster (HNEt3)2[(UO2)4(O)2(SC5NH4)6].cntdot.Me2CO Inorganic Chemistry. ,vol. 33, pp. 5167- 5168 ,(1994) , 10.1021/IC00101A004
S. Siegel, A. Viste, H. R. Hoekstra, B. Tani, The structure of hydrogen triuranate Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 28, pp. 117- 121 ,(1972) , 10.1107/S0567740872001931
A. Perrin, J.-Y. Le Marouille, Structure cristalline et moléculaire du complexe tétranucléaire K2(UO2)4O2‐(OH)2Cl4(H2O)6 Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 33, pp. 2477- 2481 ,(1977) , 10.1107/S0567740877008759
Seiji Shinkai, Hiroshi Koreishi, Kaori Ueda, Takashi Arimura, Osamu Manabe, Molecular design of calixarene-based uranophiles which exhibit remarkably high stability and selectivity Journal of the American Chemical Society. ,vol. 109, pp. 6371- 6376 ,(1987) , 10.1021/JA00255A023
A. Perrin, Preparation, etude structurale et vibrationnelle des complexes M2U2O5Cl4, 2H2O (M = Rb, Cs): Mise en evidence d'un anion tetranucleaire |(UO2)4O2Cl8(H2O)2|4− Journal of Inorganic and Nuclear Chemistry. ,vol. 39, pp. 1169- 1172 ,(1977) , 10.1016/0022-1902(77)80339-4
G. M. Sheldrick, Phase annealing in SHELX-90: direct methods for larger structures Acta Crystallographica Section A Foundations of Crystallography. ,vol. 46, pp. 467- 473 ,(1990) , 10.1107/S0108767390000277
Mutikainen I, Haemaelaeinen R, Orama O, Turpeinen U, ビス[(2‐ヒドロキシエチル)ジメチルアンモニウム]・ビス[μ‐アセタト‐O:O′‐アセタト‐O,O′‐μ‐(2‐ジメチルアミノエタノラト‐N,μ‐O)‐μ3‐オキソテトラオキソ二ウラン(VI)酸塩] Acta Crystallogr Sect C. ,vol. 52, pp. 1169- 1171 ,(1996)