Synthesis of the novel anions [Re3H3(μ3-OR)(CO)9]− (R = Et, i-Pr, t-Bu) and x-ray characterization of [Re3H3(μ3-OEt)(CO)9](NEt4
作者： Gianfranco Ciani , Giuseppe D'Alfonso , Maria Freni , Pierfrancesco Romiti , Angelo Sironi
DOI: 10.1016/S0022-328X(00)83020-X
关键词:
摘要: Abstract The novel anions [Re3H3(μ3-OR)(CO)9]− (R = Et, i-Pr, t-Bu) have been obtained by reaction of the unsaturated anion [Re3H4(CO)10]− with corresponding alcohols. They characterized IR and NMR spectra an X-ray diffraction study ethoxy species, which contains equilateral metal atoms triangle (mean ReRe 2.994 ») nine terminal CO groups, three for each metal, a triply-bridging ligand ReO 2.17 »). hydride ligands are bridging on edges Re3 triangle.
elsevier.com
sci-hub.se 参考文章(8)
G. Ciani, G. D'Alfonso, M. Freni, P. Romiti, A. Sironi, Reactions of the unsaturated anions [H3Re3(CO)10]2− and [H4Re3(CO)10]− with iodine in various solvents. X-ray characterization of the derivative H3Re3(CO)10(py)2 Journal of Organometallic Chemistry. ,vol. 186, pp. 353- 360 ,(1980) , 10.1016/S0022-328X(00)82416-X
M. Freni, P. Romiti, G. D'Alfonso, Synthesis and characterization of three hydridocarbonylrhenium clusters Journal of Organometallic Chemistry. ,vol. 140, pp. 195- 202 ,(1977) , 10.1016/S0022-328X(00)93195-4
R. Mason, D.M.P. Mingos, Geometries of and bonding in bi- and polynuclear metal complexes with bridging ligands Journal of Organometallic Chemistry. ,vol. 50, pp. 53- 61 ,(1973) , 10.1016/S0022-328X(00)95088-5
R. Mason, Structural inorganic chemistry and diffraction methods: metal-ligand bonds in polynuclear complexes and on metal surfaces Pure and Applied Chemistry. ,vol. 33, pp. 513- 526 ,(1973) , 10.1351/PAC197333040513
A. Bertolucci, M. Freni, P. Romiti, G. Ciani, A. Sironi, V.G. Albano, Synthesis and x-ray chracterization of the dianions trihydridodecacarbonyltrirhenate(2—)and trihydrido-μ3-oxoenneacarbonyltrirhenate(2—) Journal of Organometallic Chemistry. ,vol. 113, ,(1976) , 10.1016/S0022-328X(00)96153-9
G. Ciani, D. D'Alfonso, M. Freni, P. Romiti, A. Sironi, A. Albinati, Synthesis and x-ray structure of the anion tetra-μ-hydridodecacarbonyl-triangulo-trirhenate(1-) Journal of Organometallic Chemistry. ,vol. 136, ,(1977) , 10.1016/S0022-328X(00)93752-5
Gianfranco Ciani, Angelo Sironi, Vincenzo G. Albano, Crystal and molecular structure of bis(tetraethylammonium) 1,2;2,3;3,1-tri-µ-hydrido-µ3,-oxo-1,1,1,2,2,2,3,3,3-enneacarbonyl-triangulo-trirhenate(2–) J. Chem. Soc., Dalton Trans.. pp. 1667- 1670 ,(1977) , 10.1039/DT9770001667
Kazi A. Azam, Antony J. Deeming, Richard E. Kimber, Padmaja R. Shukla, Metallation of hydroxy-aryl and -alkyl compounds by reaction with dodecacarbonyl-triangulo-triosmium Journal of The Chemical Society-dalton Transactions. pp. 1853- 1858 ,(1976) , 10.1039/DT9760001853