Easily reversible ionic fragmentation of a tetrahedral unsaturated rhenium cluster, a reappraisal of the reaction of [Re4(µ3-H)4(CO)12] with methanol
作者： Tiziana Beringhelli , Giuseppe D'Alfonso
DOI: 10.1039/C39940002631
关键词:
摘要: The unsaturated tetrahedral cluster [Re4(µ3-H)4(CO)12] in the presence of weak donor molecules L, like methanol or acetone, reversibly fragments to triangular anions and mononuclear cations, probably via spiked-triangular [Re4(µ-H)4(CO)12L4] intermediates.
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