A simple single-step synthesis of [99Tc3H3(CO)12] from [99TcO4]–and its X-ray crystal structure. Application to the production of no-carrier added [188Re3H3(CO)12]
作者： Roger Alberto , Roger Schibli , P. August Schubiger , Ulrich Abram , Rainer Hübener
DOI: 10.1039/CC9960001291
关键词:
摘要: Reduction of no-carrier added [188ReO4]–(ng range) in thf–[NBu4]Cl with BH3·thf under an atmosphere CO yields [188ReCl3(CO)3]2– and [188Re3(µ-H)3(CO)12]; similar conditions as [188ReO4]–, the first µ-hydrido-bridged 99Tc hydrido carbonyl complex is prepared structurally characterised.
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