Serendipity and Rational Design of One‐Dimensional Doubly Stranded Chains with Nanometric Cavities Based on AgI Coordination Chemistry
作者： Lamia Mimassi , Carine Guyard-Duhayon , Laurence Raehm , Hani Amouri
DOI: 10.1002/1099-0682(200209)2002:9<2453::AID-EJIC2453>3.0.CO;2-L
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摘要: Spontaneous and cooperative self-assembly processes allowed the preparation of two complexes {[AgL1 2][X]}n [X = CF3SO3, (3a); X BF4, (3b)] in quantitative yields, identified as 1-D doubly stranded chains. The X-ray molecular structures 3a,b are reported. Complexes isostructural crystallize triclinic unit cell. 3a 3b show formation a one-dimensional coordination polymer exhibiting an outstanding feature presence infinite chained metallomacrocycles with nanometric cavit-
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