A unique type of a dicobalt cage templated by a weakly coordinated hexafluorophosphate anion: design, structure and solid-state NMR investigations
作者： Christophe Desmarets , Fabrizia Poli , Xavier F. Le Goff , Klaus Müller , Hani Amouri
DOI: 10.1039/B918888F
关键词:
摘要: A dinuclear cobalt capsule [PF6⊂(CH3CN)2(Co2L4)][PF6]3 (2), (L = bis-benzimidazole-1,3-phenylene) has been prepared using a self-assembly approach. This unique class of cage is perfectly designed to encapsulate weakly coordinated anions, i.e. BF4− and PF6−via an M⋯anion weak interaction as illustrated by X-ray solid-state NMR investigations. Selective anion binding for over PF6− also observed.
rsc.org
sci-hub.se 参考文章(45)
Rolf W. Saalfrank, Bernhard Demleitner, Horst Glaser, Harald Maid, Daniela Bathelt, Frank Hampel, Walter Bauer, Markus Teichert, Enantiomerisation of Tetrahedral Homochiral [M4L6] Clusters: Synchronized Four Bailar Twists and Six Atropenantiomerisation Processes Monitored by Temperature‐Dependent Dynamic 1H NMR Spectroscopy Chemistry: A European Journal. ,vol. 8, pp. 2679- 2683 ,(2002) , 10.1002/1521-3765(20020617)8:12<2679::AID-CHEM2679>3.0.CO;2-7
Cheng-Yong Su, Yue-Peng Cai, Chun-Long Chen, Hua-Xin Zhang, Bei-Sheng Kang, Coordination-directed assembly of trigonal and tetragonal molecular boxes encapsulating anionic guests Journal of The Chemical Society-dalton Transactions. pp. 359- 361 ,(2001) , 10.1039/B010118O
Stefan Leininger, Bogdan Olenyuk, Peter J. Stang, Self-Assembly of Discrete Cyclic Nanostructures Mediated by Transition Metals Chemical Reviews. ,vol. 100, pp. 853- 908 ,(2000) , 10.1021/CR9601324
Markus Albrecht, Yufeng Liu, Sascha S. Zhu, Christoph A. Schalley, Roland Fröhlich, Self-assembly of heterodinuclear triple-stranded helicates: control by coordination number and charge Chemical Communications. pp. 1195- 1197 ,(2009) , 10.1039/B821819F
Adrian R. Brough, Clare P. Grey, Christopher M. Dobson, Paramagnetic ions as structural probes in solid-state NMR: Distance measurements in crystalline lanthanide acetates Journal of the American Chemical Society. ,vol. 115, pp. 7318- 7327 ,(1993) , 10.1021/JA00069A034
Roman Dembinski, Tamás Bartik, Berit Bartik, Monika Jaeger, J. A. Gladysz, Toward Metal-Capped One-Dimensional Carbon Allotropes: Wirelike C6−C20 Polyynediyl Chains That Span Two Redox-Active (η5-C5Me5)Re(NO)(PPh3) Endgroups Journal of the American Chemical Society. ,vol. 122, pp. 810- 822 ,(2000) , 10.1021/JA992747Z
Rowena L. Paul, Stephen P. Argent, John C. Jeffery, Lindsay P. Harding, Jason M. Lynam, Michael D. Ward, Structures and anion-binding properties of M4L6 tetrahedral cage complexes with large central cavities. Dalton Transactions. pp. 3453- 3458 ,(2004) , 10.1039/B409809A
Lamia Mimassi, Carine Guyard-Duhayon, Laurence Raehm, Hani Amouri, Serendipity and Rational Design of One‐Dimensional Doubly Stranded Chains with Nanometric Cavities Based on AgI Coordination Chemistry European Journal of Inorganic Chemistry. ,vol. 2002, pp. 2453- 2457 ,(2002) , 10.1002/1099-0682(200209)2002:9<2453::AID-EJIC2453>3.0.CO;2-L
Tamás Bartik, Weiqing Weng, James A. Ramsden, Slawomir Szafert, Stephen B. Falloon, Atta M. Arif, J. A. Gladysz, New Forms of Coordinated Carbon: Wirelike Cumulenic C3 and C5 sp Carbon Chains that Span Two Different Transition Metals and Mediate Charge Transfer Journal of the American Chemical Society. ,vol. 120, pp. 11071- 11081 ,(1998) , 10.1021/JA981927Q
I. Solomon, Relaxation Processes in a System of Two Spins Physical Review. ,vol. 99, pp. 559- 565 ,(1955) , 10.1103/PHYSREV.99.559