Single Water Molecule Recognition: A 1:1 Complex of Crownophane with Water by Pseudo-tetrahedral Hydrogen Bond Formation

作者: Kazuhisa Hiratani , Midori Goto , Yoshinobu Nagawa , Kazuyuki Kasuga , Kyoko Fujiwara

DOI: 10.1246/CL.2000.1364

关键词:

摘要: A 22-membered crownophane prepared via the “Tandem Claisen Rearrangement” was found to form stable 1:1 complex with water, which is incorporated into cavity by pseudo-tetrahedral hydrogen bond formation and observed DSC, TGA, X-ray structural analysis.

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