作者: Seiichi Inokuma , Shigefumi Sakai , Jun Nishimura
DOI: 10.1007/BFB0025268
关键词: Crystallography 、 Chemistry 、 Crown Compounds 、 Stacking 、 Hydrophobic effect 、 Crown ether 、 Complementarity (molecular biology)
摘要: Crown compounds having cyclophane-skeletons and called “crownophanes”, are reviewed. They form characteristic host-guest complexes due to their crown-cyclophane hybrid structures. Significant stabilization of is often reported through the ion-dipole, cation-aromatic π-electron π-π stacking interactions, size-and-shape complementarity, hydrophobic interaction.