Syntheses and ionophoric properties of crownophanes

作者: Seiichi Inokuma , Shigefumi Sakai , Jun Nishimura

DOI: 10.1007/BFB0025268

关键词: CrystallographyChemistryCrown CompoundsStackingHydrophobic effectCrown etherComplementarity (molecular biology)

摘要: Crown compounds having cyclophane-skeletons and called “crownophanes”, are reviewed. They form characteristic host-guest complexes due to their crown-cyclophane hybrid structures. Significant stabilization of is often reported through the ion-dipole, cation-aromatic π-electron π-π stacking interactions, size-and-shape complementarity, hydrophobic interaction.

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