A surprise from 1954: siloxane equilibration is a simple, robust, and obvious polymer self-healing mechanism.
作者： Peiwen Zheng , Thomas J. McCarthy
DOI: 10.1021/JA2113257
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摘要: Tetramethylammonium silanolate-initiated ring-opening copolymerization of octamethylcyclotetrasiloxane (D 4 ) and bis(heptamethylcyclotetrasiloxanyl)ethane (bis-D 4 ) renders …
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