Perylene as an electron-rich moiety in healable, complementary π–π stacked, supramolecular polymer systems
作者： Lewis R. Hart , Ngoc A. Nguyen , Josephine L. Harries , Michael E. Mackay , Howard M. Colquhoun
DOI: 10.1016/J.POLYMER.2015.03.028
关键词:
摘要: A two-component, supramolecular polymer blend has been designed using a novel π-electron rich bis-perylene-terminated polyether. This polymer is able to self-assemble through electronically complementary π–π stacking interactions with a π-electron-deficient chain-folding polydiimide to afford thermally healable polymer blends. Model compounds were developed to assess the suitability of the deep green complexes formed between perylene residues and chain-folding bis-diimides for use in polymer blends. The polymer …
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