Enhanced photocurrent and stability of organic solar cells using solution-based NiO interfacial layer
作者： Kim Hai Wong , Krishnamoorthy Ananthanarayanan , Marc Daniel Heinemann , Joachim Luther , Palani Balaya
DOI: 10.1016/J.SOLENER.2012.08.004
关键词:
摘要: Metal oxide semiconductors are promising interfacial materials for organic photovoltaics (OPVs) because of their electrical properties and solution processability. In this article, we report the fabrication poly(3-hexylthiophene):[6,6]-phenyl-C61 butyric acid methyl ester (P3HT:PCBM) OPV devices incorporating solution-based NiO layers that show enhancements device photocurrent stability. We discuss impact parasitic shunt series resistances on performance as well ambient degradation these devices, studied with intensity modulated spectroscopy (IMPS). The results showed charge extraction was predominantly affected by via decrease in carrier mobility increased trapping/recombination, revealing physical mechanism behind observed. 2012 Elsevier Ltd. All rights reserved.
harvard.edu
elsevier.com
sci-hub.se 参考文章(28)
Joshua C. Byers, Scott Ballantyne, Konstantin Rodionov, Alex Mann, O. A. Semenikhin, Mechanism of Recombination Losses in Bulk Heterojunction P3HT:PCBM Solar Cells Studied Using Intensity Modulated Photocurrent Spectroscopy ACS Applied Materials & Interfaces. ,vol. 3, pp. 392- 401 ,(2011) , 10.1021/AM100998T
Andrea Seemann, Tobias Sauermann, Christoph Lungenschmied, Oskar Armbruster, Siegfried Bauer, H.-J. Egelhaaf, Jens Hauch, Reversible and irreversible degradation of organic solar cell performance by oxygen Solar Energy. ,vol. 85, pp. 1238- 1249 ,(2011) , 10.1016/J.SOLENER.2010.09.007
Juan C. De Jesus, Ismael González, Angel Quevedo, Tito Puerta, Thermal decomposition of nickel acetate tetrahydrate: an integrated study by TGA, QMS and XPS techniques Journal of Molecular Catalysis A-chemical. ,vol. 228, pp. 283- 291 ,(2005) , 10.1016/J.MOLCATA.2004.09.065
Gwan Ho Jung, Kyung-Geun Lim, Tae-Woo Lee, Jong-Lam Lee, Morphological and electrical effect of an ultrathin iridium oxide hole extraction layer on P3HT:PCBM bulk-heterojunction solar cells Solar Energy Materials and Solar Cells. ,vol. 95, pp. 1146- 1150 ,(2011) , 10.1016/J.SOLMAT.2010.12.039
Yoshiki Kinoshita, Rie Takenaka, Hideyuki Murata, Independent control of open-circuit voltage of organic solar cells by changing film thickness of MoO3 buffer layer Applied Physics Letters. ,vol. 92, pp. 243309- ,(2008) , 10.1063/1.2949321
Vishal Shrotriya, Gang Li, Yan Yao, Chih-Wei Chu, Yang Yang, Transition metal oxides as the buffer layer for polymer photovoltaic cells Applied Physics Letters. ,vol. 88, pp. 073508- ,(2006) , 10.1063/1.2174093
Sun-Young Park, Hye-Ri Kim, Yong-Jin Kang, Dong-Ho Kim, Jae-Wook Kang, Organic solar cells employing magnetron sputtered p-type nickel oxide thin film as the anode buffer layer Solar Energy Materials and Solar Cells. ,vol. 94, pp. 2332- 2336 ,(2010) , 10.1016/J.SOLMAT.2010.08.004
P.M. DiCarmine, O.A. Semenikhin, Intensity modulated photocurrent spectroscopy (IMPS) of solid-state polybithiophene-based solar cells Electrochimica Acta. ,vol. 53, pp. 3744- 3754 ,(2008) , 10.1016/J.ELECTACTA.2007.06.057
Rafael Betancur, Marc Maymó, Xavier Elias, Luat T. Vuong, Jordi Martorell, Sputtered NiO as electron blocking layer in P3HT:PCBM solar cells fabricated in ambient air Solar Energy Materials and Solar Cells. ,vol. 95, pp. 735- 739 ,(2011) , 10.1016/J.SOLMAT.2010.10.014
K. Xerxes Steirer, Jordan P. Chesin, N. Edwin Widjonarko, Joseph J. Berry, Alex Miedaner, David S. Ginley, Dana C. Olson, Solution deposited NiO thin-films as hole transport layers in organic photovoltaics Organic Electronics. ,vol. 11, pp. 1414- 1418 ,(2010) , 10.1016/J.ORGEL.2010.05.008