Interactions of supported nickel and nickel oxide catalysts with methane and steam at high temperatures
作者： Pooya Azadi , Junichiro Otomo , Hiroyuki Hatano , Yoshito Oshima , Ramin Farnood
DOI: 10.1016/J.CES.2011.06.002
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摘要: Abstract The catalytic performance of cermets made 10% nickel or oxide supported on YSZ (yttria-stabilized zirconia) for chemical looping combustion (CLC) and steam reforming (SR) methane at 700 °C is investigated. Steam over the reduced catalyst resulted in a syngas containing more than 70% hydrogen about 15% carbon monoxide. Chemical with insufficient lattice oxygen could potentially lead to 40–65% rich gas products. Prolonged induction period (e.g. 30–80 min) reduction by has been observed presence steam. span increases increasing partial pressure. It hypothesized that delayed related retarding effect autocatalytic reactions subsequent reactions.
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sci-hub.se 参考文章(19)
Andrew Murray, Cell cycle: A snip separates sisters Nature. ,vol. 400, pp. 19- 21 ,(1999) , 10.1038/21781
E. Perry Murray, T. Tsai, S. A. Barnett, A direct-methane fuel cell with a ceria-based anode Nature. ,vol. 400, pp. 649- 651 ,(1999) , 10.1038/23220
Tobias Pröll, Johannes Bolhàr-Nordenkampf, Philipp Kolbitsch, Hermann Hofbauer, Syngas and a separate nitrogen/argon stream via chemical looping reforming – A 140 kW pilot plant study Fuel. ,vol. 89, pp. 1249- 1256 ,(2010) , 10.1016/J.FUEL.2009.09.033
Tobias Mattisson, Anders Lyngfelt, Paul Cho, The use of iron oxide as an oxygen carrier in chemical-looping combustion of methane with inherent separation of CO2 Fuel. ,vol. 80, pp. 1953- 1962 ,(2001) , 10.1016/S0016-2361(01)00051-5
Qamar Zafar, Alberto Abad, Tobias Mattisson, Börje Gevert, Reaction Kinetics of Freeze-Granulated NiO/MgAl2O4 Oxygen Carrier Particles for Chemical-Looping Combustion Energy & Fuels. ,vol. 21, pp. 610- 618 ,(2007) , 10.1021/EF060450Y
Hiroyuki Hatano, Low temperature gasification using lattice oxygen Chemical Engineering Science. ,vol. 65, pp. 47- 53 ,(2010) , 10.1016/J.CES.2009.01.061
Masaru Ishida, Hongguang Jin, A Novel Combustor Based on Chemical-Looping Reactions and Its Reaction Kinetics Journal of Chemical Engineering of Japan. ,vol. 27, pp. 296- 301 ,(1994) , 10.1252/JCEJ.27.296
J Richardson, X-ray diffraction study of nickel oxide reduction by hydrogen Applied Catalysis A-general. ,vol. 246, pp. 137- 150 ,(2003) , 10.1016/S0926-860X(02)00669-5
Magnus Rydén, Anders Lyngfelt, Tobias Mattisson, Synthesis gas generation by chemical-looping reforming in a continuously operating laboratory reactor Fuel. ,vol. 85, pp. 1631- 1641 ,(2006) , 10.1016/J.FUEL.2006.02.004
R. Barfod, A. Hagen, S. Ramousse, P. V. Hendriksen, M. Mogensen, Break down of losses in thin electrolyte SOFCs Fuel Cells. ,vol. 6, pp. 141- 145 ,(2006) , 10.1002/FUCE.200500113