Impact of industrial and mine drainage wastes on the heavy metal distribution in the drainage basin and estuary of the Sado River (Portugal).

作者: Philippe Quevauviller , Renaud Lavigne , Leopoldo Cortez

DOI: 10.1016/0269-7491(89)90155-3

关键词:

摘要: This paper presents results from a survey of the heavy metal distribution in sediments drainage basin and estuary Sado River (Portugal). In basin, metals originate mostly pyrite outcrop erosion mining activities (Cd, Zn, Cu locally Hg, Pg), also crust (Sn, Ni, Ti, Zr). These sources are not correlated with particulate organic carbon (POC) so thought to be inorganic forms this area. Anthropogenic (urban industrial) found lower Cd, Pb Cu) along high POC concentrations. zone, these strongly adsorbed onto particles. Furthermore, organo-metallic species likely present, as demonstrated case Sn, since methyl- butyl-tin were detected suggests need for detection understand geochemical cycles. No long-term changes concentrations sediment cores, except middle (Zn, due development on an industrial scale 1860s.

参考文章(13)
Ingemar Cato, Eric Olausson, Chemistry and biogeochemistry of estuaries ,(1980)
Jean-Marie Martin, Michel Meybeck, Elemental mass-balance of material carried by major world rivers Marine Chemistry. ,vol. 7, pp. 173- 206 ,(1979) , 10.1016/0304-4203(79)90039-2
L.S. Balistrieri, J.W. Murray, The adsorption of Cu, Pb, Zn, and Cd on goethite from major ion seawater Geochimica et Cosmochimica Acta. ,vol. 46, pp. 1253- 1265 ,(1982) , 10.1016/0016-7037(82)90010-2
L.J.G. Schermerhorn, The deposition of volcanics and pyritite in the Iberian Pyrite Belt Mineralium Deposita. ,vol. 5, pp. 273- 279 ,(1970) , 10.1007/BF00201992
Olivier F. X. Donard, Spyridon. Rapsomanikis, James H. Weber, Speciation of inorganic tin and alkyltin compounds by atomic absorption spectrometry using electrothermal quartz furnace after hydride generation Analytical Chemistry. ,vol. 58, pp. 772- 777 ,(1986) , 10.1021/AC00295A027
O Donard, Ph Pedemay, Improvements in the determination of mercury by cold-vapor atomic absorption spectrometry Analytica Chimica Acta. ,vol. 153, pp. 301- 305 ,(1983) , 10.1016/S0003-2670(00)85519-1
A. Tessier, F. Rapin, R. Carignan, Trace metals in oxic lake sediments: possible adsorption onto iron oxyhydroxides Geochimica et Cosmochimica Acta. ,vol. 49, pp. 183- 194 ,(1985) , 10.1016/0016-7037(85)90203-0