Comparative molecular chemistry of molybdenum and tungsten and its relation to hydroxylase and oxotransferase enzymes
作者： Richard H. Holm , Edward I. Solomon , Amit Majumdar , Adam Tenderholt
DOI: 10.1016/J.CCR.2010.10.017
关键词:
摘要: The similarities and differences in the fundamental coordination chemistry of molybdenum tungsten mainly physiological oxidation states MIV–VI are examined relation to properties enzyme sites that catalyze oxygen atom transfer reactions. comparative aspects dithiolene complexes, which as synthetic analogues simulate structural electronic features these sites, emphasized. Analogue reaction systems enzymes summarized. mechanism reduction biological substrate Me2SO one such system elucidated with density functional calculations is presented a case study.
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