Synthesis and luminescent properties of nanoparticles LaSrAl3O7:Eu, Tb

作者: Amurisana Bao , Hua Yang , Chunyan Tao

DOI: 10.1016/J.CAP.2009.02.008

关键词:

摘要: Abstract Phosphors of nanoparticles LaSrAl3O7:RE3+(RE Eu, Tb) have been prepared by a sol–gel method. The structure and luminescent properties LaSrAl3O7:Eu3+ LaSrAl3O7:Tb3+ phosphors were characterized X-ray diffraction atomic force microscopy (AFM), photoluminescence excitation emission spectra utilized. From (XRD) patterns, it is indicated that the phosphor LaSrAl3O7 forms without impurity phase at 900 °C. (AFM) images, shown crystal size phosphores are about 60–80 nm. Upon with UV irradiation, there strong around 617 nm corresponding to forced electric dipole 5D0–7F2 transition Eu3+, 545 nm 5D4–7F5 Tb3+. dependence intensity on Eu3+(or Tb3+) concentration annealing temperature also studied in detail.

参考文章(22)
P. A. M. Berdowski, M. J. J. Lammers, G. Blasse, 5D3–5D4 cross relaxation in Tb3+ pairs in CsCdBr3 crystals Journal of Chemical Physics. ,vol. 83, pp. 476- 479 ,(1985) , 10.1063/1.449562
M Kaczkan, I Pracka, M Malinowski, Optical transitions of Ho3+ in SrLaGa3O7 Optical Materials. ,vol. 25, pp. 345- 352 ,(2004) , 10.1016/J.OPTMAT.2003.08.003
Zongquan Li, H. Hahn, R.W. Siegel, New phases of erbium oxides Materials Letters. ,vol. 6, pp. 342- 346 ,(1988) , 10.1016/0167-577X(88)90119-X
Liya Zhou, Wallace C.H. Choy, Jianxin Shi, Menglian Gong, Hongbin Liang, T.I. Yuk, Synthesis, vacuum ultraviolet and near ultraviolet-excited luminescent properties of GdCaAl3O7: RE3+ (RE=Eu, Tb) Journal of Solid State Chemistry. ,vol. 178, pp. 3004- 3009 ,(2005) , 10.1016/J.JSSC.2005.07.012
M.A. Scott, T.P.J. Han, H.G. Gallagher, B. Henderson, Near-infrared laser crystals based on 3d2 ions Spectroscopic studies of 3d2 ions in oxide, melilite and apatite crystals Journal of Luminescence. pp. 260- 262 ,(1997) , 10.1016/S0022-2313(96)00388-2
N Kodama, Y Tanii, M Yamaga, Optical properties of long-lasting phosphorescent crystals Ce3+-doped Ca2Al2SiO7 and CaYAl3O7 Journal of Luminescence. ,vol. 87, pp. 1076- 1078 ,(2000) , 10.1016/S0022-2313(99)00543-8
Shun-ichi Kubota, Makoto Izumi, Hisanori Yamane, Masahiko Shimada, Luminescence of Eu3+, Tb3+ and Tm3+ in SrLaGa3O7 Journal of Alloys and Compounds. ,vol. 283, pp. 95- 101 ,(1999) , 10.1016/S0925-8388(98)00866-4
Anne-Marie Lozac'h, Micheline Guittard, Jean Flahaut, Sur une nouvelle famille de combinaisons soufrees, de type “melilite” Materials Research Bulletin. ,vol. 8, pp. 75- 85 ,(1973) , 10.1016/0025-5408(73)90096-2
M. Malinowski, I. Pracka, B. Surma, T. Łukasiewicz, W. Woliński, R. Wolski, Spectroscopic and laser properties of SrLaGa3O7:Pr3+ crystals Optical Materials. ,vol. 6, pp. 305- 312 ,(1996) , 10.1016/S0925-3467(96)00048-1
W Ryba-Romanowski, S Goła̧b, G Dominiak-Dzik, W.A Pisarski, M Berkowski, J Fink-Finowicki, Growth and spectroscopy of chromium doped SrXGa3O7 (X=La, Gd) crystals Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 54, pp. 2071- 2075 ,(1998) , 10.1016/S1386-1425(98)00119-X