Performance analysis of a capacitive deionization stack for brackish water desalination

作者: Julio J. Lado , Vincenzo Cartolano , Enrique García-Quismondo , Guzmán García , Ignacio Almonacid

DOI: 10.1016/J.DESAL.2020.114912

关键词:

摘要: Abstract Capacitive deionization (CDI), a promising ion removal technology, has shown encouraging results in the last decade. In this work comprehensive characterization of CDI prototype equipped with 3D graphite felt electrodes is shown. Initially, study different flow distributor designs, analyzed by Computational Flow Dynamic (CFD), determined importance elements such as small inlet cavities or perforated channels to achieve uniform fluid distribution. Then, an evaluation under operational parameters and modes (batch single pass, SP) demonstrated strong flexibility terms performance that system able offer. Thus, general terms, SP experiments were produce larger quantities water (14–47 L h−1 m−2) than batch (2–24 L h−1 m−2) although obtaining lower salt concentration reductions (1–2 mM vs 6–10 mM, respectively). The stack was tested for 350 galvanostatic cycles (700 h operation) showing exceptional robustness performance. Energy consumption values below 200 Wh m−3 obtained experiments, whereas value increased 600 Wh m−3 tests. Nevertheless, implementing energy recovery these could be reduced average 40–50%.

参考文章(55)
Julio J. Lado, Rodolfo E. Pérez-Roa, Jesse J. Wouters, M. Isabel Tejedor-Tejedor, Cade Federspill, Marc A. Anderson, Continuous cycling of an asymmetric capacitive deionization system: An evaluation of the electrode performance and stability Journal of environmental chemical engineering. ,vol. 3, pp. 2358- 2367 ,(2015) , 10.1016/J.JECE.2015.08.025
Kun-Lin Yang, Tung-Yu Ying, Sotira Yiacoumi, Costas Tsouris, E. Steven Vittoratos, Electrosorption of ions from aqueous solutions by carbon aerogel: An electrical double-layer model Langmuir. ,vol. 17, pp. 1961- 1969 ,(2001) , 10.1021/LA001527S
Vitezslav Benda, Nader Barsoum, Jeffrey Frank Webb, Pandian Vasant, POWER SEMICONDUCTORS—STATE OF ART AND FUTURE TRENDS PROCEEDINGS OF THE FOURTH GLOBAL CONFERENCE ON POWER CONTROL AND OPTIMIZATION. ,vol. 1337, pp. 16- 24 ,(2011) , 10.1063/1.3592437
Izaak Cohen, Eran Avraham, Yaniv Bouhadana, Abraham Soffer, Doron Aurbach, Long term stability of capacitive de-ionization processes for water desalination: The challenge of positive electrodes corrosion Electrochimica Acta. ,vol. 106, pp. 91- 100 ,(2013) , 10.1016/J.ELECTACTA.2013.05.029
R. Zhao, O. Satpradit, H.H.M. Rijnaarts, P.M. Biesheuvel, A. van der Wal, Optimization of salt adsorption rate in membrane capacitive deionization Water Research. ,vol. 47, pp. 1941- 1952 ,(2013) , 10.1016/J.WATRES.2013.01.025
Soowhan Kim, Edwin Thomsen, Guanguang Xia, Zimin Nie, Jie Bao, Kurtis Recknagle, Wei Wang, Vilayanur Viswanathan, Qingtao Luo, Xiaoliang Wei, Alasdair Crawford, Greg Coffey, Gary Maupin, Vincent Sprenkle, 1 kW/1 kWh advanced vanadium redox flow battery utilizing mixed acid electrolytes Journal of Power Sources. ,vol. 237, pp. 300- 309 ,(2013) , 10.1016/J.JPOWSOUR.2013.02.045
Haibo Li, Linda Zou, Likun Pan, Zhuo Sun, Novel Graphene-Like Electrodes for Capacitive Deionization Environmental Science & Technology. ,vol. 44, pp. 8692- 8697 ,(2010) , 10.1021/ES101888J
Laurent Hardy, Alberto Garrido, Luis Juana, Evaluation of Spain's Water-Energy Nexus International Journal of Water Resources Development. ,vol. 28, pp. 151- 170 ,(2012) , 10.1080/07900627.2012.642240