The preparation and colour of tris-2,2′-bipyridyl- and bis-2,2′,2″-terpyridylrhodium(III) salts

作者: C.M. Harris , E.D. McKenzie

DOI: 10.1016/0022-1902(63)80005-6

关键词:

摘要: Abstract The preparation of the two series salts [Rh(2,2′-bipyridyl)3]X3 and [Rh(2,2′,2″-terpyridyl)2]X3 (where X = Cl, Br, I, SCN, ClO4) is described. colours these are interpreted in terms charge transfer from anions to colourless cations.

参考文章(6)
L. E. Orgel, Charge-transfer spectra and some related phenomena Quarterly Reviews, Chemical Society. ,vol. 8, pp. 422- 450 ,(1954) , 10.1039/QR9540800422
D. A. L. Hope, R. J. Otter, J. E. Prue, 1006. The optical behaviour of electrolyte solutions Journal of The Chemical Society (resumed). pp. 5226- 5233 ,(1960) , 10.1039/JR9600005226
B. Martin, Gwyneth M. Waind, 869. 2 : 2′-Dipyridyl complexes of cobalt, rhodium, and iridium. Part I. Tervalent rhodium and iridium complexes Journal of The Chemical Society (resumed). pp. 4284- 4288 ,(1958) , 10.1039/JR9580004284