Synthesis and thermal investigations of [Rh(bpy)3]X3 (bpy = 2,2'-dipyridyl; X = Cl−, Br−, I−, ReO−4) and [Rh(bpy)3][CdnX2n+3] (X = Cl−, Br−, I−) type complexes
作者： A. Bujewski , M. Walewski , K. Grzȩzicki
DOI: 10.1016/0040-6031(91)80120-8
关键词:
摘要: Abstract New methods of synthesis [Rh(bpy)3]X3(aq.) (X = Cl or Br) have been developed, and rhodium(III) rhenate(VII), as well tris(2,2'-dipyridyl) halogenocadmates, obtained. The quantitative composition these compounds has determined on the basis chemical analysis thermal spectrophotometric investigations. A very weak outer-sphere interaction various anionic countenons with chelate cations [Rh(bpy)3]3+ type established in aqueous solution, contrast to interactions occurring solid state, indicated by results analysis.
elsevier.com
sci-hub.se 参考文章(17)
A. Bujewski, K. Grzȩdzicki, J. Dobrowolski, Preparation and thermal decomposition of halogenometalates: Part I. Tris(2,2'-Dipyridyl)ruthenium(II) halogenocadmates Thermochimica Acta. ,vol. 127, pp. 347- 354 ,(1988) , 10.1016/0040-6031(88)87510-5
M. Keith DeArmond, James E. Hillis, Luminescence of Transition Metal d6 Chelates Journal of Chemical Physics. ,vol. 54, pp. 2247- 2253 ,(1971) , 10.1063/1.1675159
A. Juris, V. Balzani, F. Barigelletti, S. Campagna, P. Belser, A. von Zelewsky, Ru(II) polypyridine complexes: photophysics, photochemistry, eletrochemistry, and chemiluminescence Coordination Chemistry Reviews. ,vol. 84, pp. 85- 277 ,(1988) , 10.1016/0010-8545(88)80032-8
Ronald R. Ruminski, Charles Letner, Synthesis and characterization of rhodium(III) complexes bound to the novel bridging ligand 2,3,5,6-tetra(2-pyridyl)pyrazine (tppz) Inorganica Chimica Acta. ,vol. 162, pp. 175- 177 ,(1989) , 10.1016/S0020-1693(00)83142-4
Quinto G Mulazzani, Silvano Emmi, Morton Z Hoffman, Margherita Venturi, None, Generation of rhodium(II) and rhodium(I) from the one-electron reduction of tris(2,2'-bipyridine)rhodium(III) ion in aqueous solution Journal of the American Chemical Society. ,vol. 103, pp. 3362- 3370 ,(1981) , 10.1021/JA00402A021
C.M. Harris, E.D. McKenzie, The preparation and colour of tris-2,2′-bipyridyl- and bis-2,2′,2″-terpyridylrhodium(III) salts Journal of Inorganic and Nuclear Chemistry. ,vol. 25, pp. 171- 174 ,(1963) , 10.1016/0022-1902(63)80005-6
A. Herbowski, J.M. Sobczak, J.J. Ziółkowski, Phosphonium salts of chloromolybdate anions Polyhedron. ,vol. 5, pp. 399- 401 ,(1986) , 10.1016/S0277-5387(00)84940-2
Fred Basolo, Stabilization of metal complexes by large counter-ions Coordination Chemistry Reviews. ,vol. 3, pp. 213- 223 ,(1968) , 10.1016/S0010-8545(00)80113-7
D.H.W Carstens, G.A Crosby, Luminescence from complexes of rhodium(III) Journal of Molecular Spectroscopy. ,vol. 34, pp. 113- 135 ,(1970) , 10.1016/0022-2852(70)90079-2
A. Bujewski, M. Walewski, K. Grzȩdzicki, J. Dobrowolski, Synthesis and thermal investigations of ruthenium(II) phenanthroline complexes of [Ru(phen)3]X2 type, where XCl−, Br−, I−, SCN−, VO3−, ReO4− Thermochimica Acta. ,vol. 159, pp. 247- 254 ,(1990) , 10.1016/0040-6031(90)80113-D