摘要: The utilization of carbon dioxide as a feedstock for the synthesis organic chemicals can contribute to more sustainable chemical industry, since CO2 is an abundant, inexpensive, and nontoxic renewable C1 resource. Nevertheless, far less attention was paid stereochemically controlled catalytic fixation/conversion processes. This review therefore aims principally showcase recent progress regarding CO2-mediated formation chiral fine chemicals, including enantioselective cyclic carbonates by asymmetric ring opening epoxides with CO2, oxazolidinones coupling reaction aziridines CO2- or base-mediated oxazolidinone from ethanolamines, metal-catalyzed functional carboxylic acids derivatives, CO2-based polycarbonates epoxides.
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