Copper–Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity
作者： Courtney E. Elwell , Nicole L. Gagnon , Benjamin D. Neisen , Debanjan Dhar , Andrew D. Spaeth
DOI: 10.1021/ACS.CHEMREV.6B00636
关键词:
摘要: A longstanding research goal has been to understand the nature and role of copper–oxygen intermediates within copper-containing enzymes abiological catalysts. Synthetic chemistry played a pivotal in highlighting viability proposed expanding library known cores. In addition number new complexes that have synthesized since previous reviews on this topic journal (Mirica, L. M.; Ottenwaelder, X.; Stack, T. D. P. Chem. Rev. 2004, 104, 1013–1046 Lewis, E. A.; Tolman, W. B. 1047–1076), field seen significant expansion (1) range cores characterized, (2) amount mechanistic work performed, particularly area organic substrate oxidation, (3) use computational methods for both corroboration prediction intermediates. The scope review limited well-characterized examples species but seeks provide ...
acs.org
sci-hub.se 参考文章(401)
Sayantan Paria, Takehiro Ohta, Yuma Morimoto, Takashi Ogura, Hideki Sugimoto, Nobutaka Fujieda, Kei Goto, Kaori Asano, Takeyuki Suzuki, Shinobu Itoh, Generation, Characterization, and Reactivity of a Cu(II)-Alkylperoxide/Anilino Radical Complex: Insight into the O-O Bond Cleavage Mechanism. Journal of the American Chemical Society. ,vol. 137, pp. 10870- 10873 ,(2015) , 10.1021/JACS.5B04104
Dipanwita Das, Yong-Min Lee, Kei Ohkubo, Wonwoo Nam, Kenneth D. Karlin, Shunichi Fukuzumi, Temperature-independent catalytic two-electron reduction of dioxygen by ferrocenes with a copper(II) tris[2-(2-pyridyl)ethyl]amine catalyst in the presence of perchloric acid. Journal of the American Chemical Society. ,vol. 135, pp. 2825- 2834 ,(2013) , 10.1021/JA312523U
Kristian E. Dalle, Franc Meyer, Modelling Binuclear Metallobiosites: Insights from Pyrazole‐Supported Biomimetic and Bioinspired Complexes European Journal of Inorganic Chemistry. ,vol. 2015, pp. 3391- 3405 ,(2015) , 10.1002/EJIC.201500185
Kazunari Yoshizawa, Methane Hydroxylation by First Row Transition Metal Oxides Wiley - VCH Verlag GmbH & CO. KGaA. pp. 317- 335 ,(2008) , 10.1002/9783527621965.CH14
Yuki Kobayashi, Kei Ohkubo, Takashi Nomura, Minoru Kubo, Nobutaka Fujieda, Hideki Sugimoto, Shunichi Fukuzumi, Kei Goto, Takashi Ogura, Shinobu Itoh, Copper(I)‐Dioxygen Reactivity in a Sterically Demanding Tripodal Tetradentate tren Ligand: Formation and Reactivity of a Mononuclear Copper(II) End‐On Superoxo Complex European Journal of Inorganic Chemistry. ,vol. 2012, pp. 4574- 4578 ,(2012) , 10.1002/EJIC.201200177
Julia Schottenheim, Claus Gernert, Benjamin Herzigkeit, Jan Krahmer, Felix Tuczek, Catalytic Models of Tyrosinase: Reactivity Differences between Systems Based on Mono‐ and Binucleating Ligands European Journal of Inorganic Chemistry. ,vol. 2015, pp. 3501- 3511 ,(2015) , 10.1002/EJIC.201500029
Hans Sterckx, Johan De Houwer, Carl Mensch, Ignacio Caretti, Kourosch Abbaspour Tehrani, Wouter A. Herrebout, Sabine Van Doorslaer, Bert U. W. Maes, Mechanism of the CuII-catalyzed benzylic oxygenation of (aryl)(heteroaryl)methanes with oxygen Chemical Science. ,vol. 7, pp. 346- 357 ,(2016) , 10.1039/C5SC03530A
Jonathan Becker, Puneet Gupta, Friedrich Angersbach, Felix Tuczek, Christian Näther, Max C. Holthausen, Siegfried Schindler, Selective Aromatic Hydroxylation with Dioxygen and Simple Copper Imine Complexes. Chemistry: A European Journal. ,vol. 21, pp. 11735- 11744 ,(2015) , 10.1002/CHEM.201501003
B. N. Sánchez-Eguía, M. Flores-Alamo, M. Orio, I. Castillo, Side-on cupric-superoxo triplet complexes as competent agents for H-abstraction relevant to the active site of PHM. Chemical Communications. ,vol. 51, pp. 11134- 11137 ,(2015) , 10.1039/C5CC02332G
Júlio C. S. Da Silva, Robert C. R. Pennifold, Jeremy N. Harvey, Willian R. Rocha, A radical rebound mechanism for the methane oxidation reaction promoted by the dicopper center of a pMMO enzyme: a computational perspective Dalton Transactions. ,vol. 45, pp. 2492- 2504 ,(2016) , 10.1039/C5DT02638E