Isomerization of pent-1-ene on novel porous solid superbase K+/ZrO2
作者： Y. Wang , A. Ji , X.W. Han , W.Y. Huang , J. Liu
DOI: 10.1016/S0167-2991(04)80570-6
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摘要: Abstract The catalytic activity and selectivity of a novel porous solid superbase K + /ZrO 2 were tested in the isomerization pent-1-ene, base strength distribution was measured non-polar system. TG-DSC-MS technique used to study decomposition KNO 3 on ZrO , characterize two evolutions NO at low above 600°C. former evolution, owing high-dispersed species, resulted formation sites, while latter appeared higher temperature, represented probably bulk potassium salt.
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sci-hub.se 参考文章(19)
You-Chang Xie, You-Qi Tang, Spontaneous Monolayer Dispersion of Oxides and Salts onto Surfaces of Supports: Applications to Heterogeneous Catalysis Advances in Catalysis. ,vol. 37, pp. 1- 43 ,(1990) , 10.1016/S0360-0564(08)60362-4
Tsutomu Yamaguchi, J.-H. Zhu, Y. Wang, Masa-aki Komatsu, Masashi Ookawa, Supported K-salts as a New Solid Base Catalyst Chemistry Letters. ,vol. 1997, pp. 989- 990 ,(1997) , 10.1246/CL.1997.989
Ying Wang, Wen Yu Huang, Yuan Chun, Jia Rong Xia, Jian Hua Zhu, Dispersion of Potassium Nitrate and the Resulting Strong Basicity on Zirconia Chemistry of Materials. ,vol. 13, pp. 670- 677 ,(2001) , 10.1021/CM000213N
J TAKE, Base-strength distribution studies of solid-base surfaces Journal of Catalysis. ,vol. 21, pp. 164- 170 ,(1971) , 10.1016/0021-9517(71)90134-5
K. Tanabe, N. Yoshii, H. Hattori, Catalytic activity and selectivity of evacuated calcium oxide for isomerization of but-1-ene Journal of The Chemical Society D: Chemical Communications. pp. 464- 464 ,(1971) , 10.1039/C29710000464
Yi Chen, Lifeng Zhang, Surface interaction model of γ -alumina-supported metal oxides Catalysis Letters. ,vol. 12, pp. 51- 62 ,(1992) , 10.1007/BF00767188
Jacek Kijeński, Stanislaw Malinowski, Influence of sodium on the physico-chemical and catalytic properties of magnesium oxide Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. ,vol. 74, pp. 250- 261 ,(1978) , 10.1039/F19787400250
Ying Wang, Jian Hua Zhu, Wen Yu Huang, Synthesis and characterization of potassium-modified alumina superbases Physical Chemistry Chemical Physics. ,vol. 3, pp. 2537- 2543 ,(2001) , 10.1039/B100084P
G. Ertl, Physical and Chemical Aspects of Adsorbents and Catalysts Zeitschrift für Physikalische Chemie. ,vol. 80, pp. 107- 107 ,(1972) , 10.1524/ZPCH.1972.80.1_2.107
Thillo Hugo Johannes Van, Andre Jacques Maurice Jules Gh, Debus Henri Robert, Lammers Rene Odon, Cahen Raymond Marc, PREPARATION OF CATALYSTS ,(1976)